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- W4200532054 abstract "Abstract A surface‐integrated form of the widely used (anharmonic) Lennard‐Jones 12–6 interaction potential, the Lennard‐Jones 9–3 potential, is used to develop a quadratic activation/driving force relationship that gives rise to asymmetric Tafel plots for electron transfer occurring with simultaneous interaction rupture. The Tafel plots are shown to exhibit linearity over a wide potential range, depending on the ratio of the Gibbs interaction well to the solvent reorganisation free energy. The fit of the model to experimental data for a ferrocene‐based self‐assembled monolayer (SAM) bathed by aqueous perchloric acid suggests ion pairing between ferricenium and perchlorate ions. This crude and primitive model readily enables experimentalists to obtain a parametric understanding of the physicochemical dynamics underpinning interaction rupture in concert with electron transfer, which may empower routes to improve the efficiency of a plethora of topical electrochemical technologies." @default.
- W4200532054 created "2021-12-31" @default.
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- W4200532054 date "2021-12-08" @default.
- W4200532054 modified "2023-09-30" @default.
- W4200532054 title "Asymmetric and Anharmonic Electrode Kinetics: Evaluation of a Model for Electron Transfer with Concerted Rupture of Weak, Inner Shell Interactions" @default.
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- W4200532054 doi "https://doi.org/10.1002/slct.202103526" @default.
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