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- W4200535306 abstract "Metal-organic frameworks (MOFs) as solid sorbents for carbon dioxide (CO2) capture face the challenge of merging efficient capture with economical regeneration in a durable, scalable material. Zinc-based Calgary Framework 20 (CALF-20) physisorbs CO2 with high capacity but is also selective over water. Competitive separations on structured CALF-20 show not just preferential CO2 physisorption below 40% relative humidity but also suppression of water sorption by CO2, which was corroborated by computational modeling. CALF-20 has a low enthalpic regeneration penalty and shows durability to steam (>450,000 cycles) and wet acid gases. It can be prepared in one step, formed as composite materials, and its synthesis can be scaled to multikilogram batches." @default.
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- W4200535306 date "2021-12-17" @default.
- W4200535306 modified "2023-10-11" @default.
- W4200535306 title "A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture" @default.
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- W4200535306 doi "https://doi.org/10.1126/science.abi7281" @default.
- W4200535306 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34914501" @default.
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