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• W4200536871 abstract "Palodesangrens A and C along with the common tetracyclic core are prepared from simple benzaldehyde and acetophenone derivatives in a 10-step longest linear sequence which featured the Diels-Alder reaction forming the cyclohexene moiety, LiAlH4 isomerization, stereoselective acid-catalyzed cyclization forming the chroman moiety, regioselective iodination/vinyl Suzuki cross-coupling reaction, and ring-closing metathesis (RCM) forming the 2H-pyran-2-one. Overall, the desired palodesangrens A and C are obtained in 6.1% and 6.4% yields, respectively." @default.
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• W4200536871 date "2021-12-14" @default.
• W4200536871 modified "2023-10-18" @default.
• W4200536871 title "Total Synthesis of Palodesangrens A and C" @default.
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• W4200536871 doi "https://doi.org/10.1021/acs.joc.1c02417" @default.
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