Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200538534> ?p ?o ?g. }
- W4200538534 abstract "Abstract Enantiopure monohydrosilanes are versatile chiral reagents for alcohol resolution and mechanistic investigation. Herein, we have demonstrated the asymmetric synthesis of monohydrosilanes via an intramolecular hydrosilylation strategy. This protocol is suitable for the synthesis of five‐ and six‐membered cyclic monohydrosilanes, including a class of chiral oxasilacycles, with excellent diastereo‐, regio‐, and enantioselectivities. Notably, the catalyst loading could be reduced to 0.1 mol % which makes this one of the most efficient methods to access chiral monohydrosilanes. Mechanistic studies and DFT calculations indicate this Rh‐catalyzed intramolecular asymmetric hydrosilylation reaction might proceed via a Chalk–Harrod mechanism, and the enantio‐determining step was predicted to be oxidative addition of Si−H bond." @default.
- W4200538534 created "2021-12-31" @default.
- W4200538534 creator A5014574735 @default.
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- W4200538534 creator A5069099445 @default.
- W4200538534 creator A5089404281 @default.
- W4200538534 date "2021-11-23" @default.
- W4200538534 modified "2023-10-17" @default.
- W4200538534 title "Enantioselective Synthesis of Silicon‐Stereogenic Monohydrosilanes by Rhodium‐Catalyzed Intramolecular Hydrosilylation" @default.
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