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- W4200567757 abstract "With the continuous research and development of amidoxime (AO)-based adsorbents, industrialization production of uranium from seawater gradually becomes a reality. However, the currently available AO-based adsorbents still suffer from low adsorption rate and poor selectivity. Herein, vertically aligned polyamioxime–graphene oxide (VA-PG) sheet membrane is fabricated by directional freeze casting. The run-through microchannels contribute to the free diffusion of uranyl ions (UO22+), leading to the fast adsorption kinetics. Furthermore, partially reduced graphene oxide allows high photothermal conversion efficiency and rapid in-plane heat transfer, resulting in the fast temperature rise under simulated sunlight irradiation. Because of the endothermic behavior of UO22+, light-irradiated VA-PG can simultaneously satisfy the requirements of high adsorption capacity (13.63 mg-U g-Ads−1), high adsorption rate (0.43 mg g−1 day−1), and excellent selectivity toward U(VI) over V(V) (U/V = 1.24) in natural seawater, indicating the right direction for a breakthrough in the field of uranium extraction from seawater." @default.
- W4200567757 created "2021-12-31" @default.
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- W4200567757 date "2021-12-19" @default.
- W4200567757 modified "2023-10-18" @default.
- W4200567757 title "Vertically Aligned Polyamidoxime/Graphene Oxide Hybrid Sheets’ Membrane for Ultrafast and Selective Extraction of Uranium from Seawater" @default.
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- W4200567757 doi "https://doi.org/10.1002/adfm.202111049" @default.
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