Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200568118> ?p ?o ?g. }
- W4200568118 endingPage "117" @default.
- W4200568118 startingPage "104" @default.
- W4200568118 abstract "Computational-experimental analysis has allowed determining that the stereochemistry of the Staudinger reaction between ketenes and imines is strongly associated with the nature of the imine, which affects the two steps of the reaction. The first step, namely the nucleophilic attack of the sp2-hybridized nitrogen atom of the imine on the sp-hybridized carbon atom of the ketene, is affected by the energetically accessible in situ isomerization patterns of the imine. The second step consists of a conrotatory electrocyclization of the zwitterionic intermediate formed in the previous step. This latter pericyclic step depends on the inward/outward torquoelectronic effects generated by the substituents of the imine. The impact of these factors on the stereochemistry of this reaction has been analyzed kinetically by numerical methods. The results of these simulations are compatible with the experimental results and support these conclusions." @default.
- W4200568118 created "2021-12-31" @default.
- W4200568118 creator A5015809186 @default.
- W4200568118 creator A5026469375 @default.
- W4200568118 creator A5027706023 @default.
- W4200568118 creator A5048069564 @default.
- W4200568118 creator A5050203638 @default.
- W4200568118 creator A5072334936 @default.
- W4200568118 creator A5082183844 @default.
- W4200568118 date "2022-01-01" @default.
- W4200568118 modified "2023-10-09" @default.
- W4200568118 title "Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines" @default.
- W4200568118 cites W148540551 @default.
- W4200568118 cites W1964881149 @default.
- W4200568118 cites W1967762257 @default.
- W4200568118 cites W1969280544 @default.
- W4200568118 cites W1970508143 @default.
- W4200568118 cites W1971933604 @default.
- W4200568118 cites W1972072636 @default.
- W4200568118 cites W1973953671 @default.
- W4200568118 cites W1975616000 @default.
- W4200568118 cites W1976245763 @default.
- W4200568118 cites W1976558839 @default.
- W4200568118 cites W1977664226 @default.
- W4200568118 cites W1980630522 @default.
- W4200568118 cites W1982527594 @default.
- W4200568118 cites W1986473729 @default.
- W4200568118 cites W1987063819 @default.
- W4200568118 cites W1987910145 @default.
- W4200568118 cites W1990627333 @default.
- W4200568118 cites W1993273339 @default.
- W4200568118 cites W1993383767 @default.
- W4200568118 cites W1995042715 @default.
- W4200568118 cites W1998944270 @default.
- W4200568118 cites W2000896423 @default.
- W4200568118 cites W2004930297 @default.
- W4200568118 cites W2008844584 @default.
- W4200568118 cites W2029107502 @default.
- W4200568118 cites W2030702360 @default.
- W4200568118 cites W2038767330 @default.
- W4200568118 cites W2041244757 @default.
- W4200568118 cites W2042944554 @default.
- W4200568118 cites W2045454660 @default.
- W4200568118 cites W2046412723 @default.
- W4200568118 cites W2046672498 @default.
- W4200568118 cites W2048106449 @default.
- W4200568118 cites W2053105966 @default.
- W4200568118 cites W2058363175 @default.
- W4200568118 cites W2061546727 @default.
- W4200568118 cites W2067357845 @default.
- W4200568118 cites W2067588895 @default.
- W4200568118 cites W2069509450 @default.
- W4200568118 cites W2070621981 @default.
- W4200568118 cites W2076618536 @default.
- W4200568118 cites W2085336624 @default.
- W4200568118 cites W2087432395 @default.
- W4200568118 cites W2090730516 @default.
- W4200568118 cites W2092954305 @default.
- W4200568118 cites W2095474273 @default.
- W4200568118 cites W2102283478 @default.
- W4200568118 cites W2102523316 @default.
- W4200568118 cites W2135096135 @default.
- W4200568118 cites W2141610565 @default.
- W4200568118 cites W2149401906 @default.
- W4200568118 cites W2150697053 @default.
- W4200568118 cites W2153072013 @default.
- W4200568118 cites W2167315885 @default.
- W4200568118 cites W2271926312 @default.
- W4200568118 cites W2312833183 @default.
- W4200568118 cites W25778730 @default.
- W4200568118 cites W2951055797 @default.
- W4200568118 cites W3004827543 @default.
- W4200568118 cites W4231649355 @default.
- W4200568118 cites W4243581949 @default.
- W4200568118 doi "https://doi.org/10.1039/d1ra06114c" @default.
- W4200568118 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35424513" @default.
- W4200568118 hasPublicationYear "2022" @default.
- W4200568118 type Work @default.
- W4200568118 citedByCount "1" @default.
- W4200568118 countsByYear W42005681182022 @default.
- W4200568118 crossrefType "journal-article" @default.
- W4200568118 hasAuthorship W4200568118A5015809186 @default.
- W4200568118 hasAuthorship W4200568118A5026469375 @default.
- W4200568118 hasAuthorship W4200568118A5027706023 @default.
- W4200568118 hasAuthorship W4200568118A5048069564 @default.
- W4200568118 hasAuthorship W4200568118A5050203638 @default.
- W4200568118 hasAuthorship W4200568118A5072334936 @default.
- W4200568118 hasAuthorship W4200568118A5082183844 @default.
- W4200568118 hasBestOaLocation W42005681181 @default.
- W4200568118 hasConcept C126661725 @default.
- W4200568118 hasConcept C147597530 @default.
- W4200568118 hasConcept C155647269 @default.
- W4200568118 hasConcept C157103358 @default.
- W4200568118 hasConcept C161790260 @default.
- W4200568118 hasConcept C171999351 @default.
- W4200568118 hasConcept C178790620 @default.
- W4200568118 hasConcept C178907741 @default.
- W4200568118 hasConcept C185592680 @default.