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- W4200623474 abstract "Co-crystallization is an efficient way of molecular crystal engineering to tune the electronic properties of organic semiconductors. In this work, we synthesized anthracene-4,8-bis(dicyanomethylene)4,8-dihydrobenzo[1,2-b:4,5-b']-dithiophene (DTTCNQ) single crystals as a template to study the crystal growth direction dependent charge transport properties and attempted to elucidate the mechanism by proposing a separate-channel charge transport model. Single-crystal anthracene-DTTCNQ field-effect transistors showed that ambipolar transport properties could be observed in all crystal growth directions. Furthermore, upon changing the measured crystal directions, the electronic properties experienced a weak change from n-type dominated ambipolar, balanced ambipolar, to p-type dominated ambipolar properties. The theoretical calculations at density functional theory (DFT) and higher theory levels suggested that the anthracene-DTTCNQ co-crystal motif was a weak charge-transfer complex, in line with the experiment. Furthermore, the detailed theoretical analysis also indicated that electron or hole transport properties originated from separated channels formed by DTTCNQ or anthracene molecules. We thus proposed a novel separate-channel transport mechanism to support additional theoretical analysis and calculations. The joint experimental and theoretical efforts in this work suggest that the engineering of co-crystallization of weak charge-transfer complexes can be a practical approach for achieving tuneable ambipolar charge transport properties by the rational choice of co-crystal formers." @default.
- W4200623474 created "2021-12-31" @default.
- W4200623474 creator A5002075675 @default.
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- W4200623474 creator A5056056743 @default.
- W4200623474 creator A5059710195 @default.
- W4200623474 creator A5087486061 @default.
- W4200623474 date "2022-01-01" @default.
- W4200623474 modified "2023-09-24" @default.
- W4200623474 title "Growth direction dependent separate-channel charge transport in the organic weak charge-transfer co-crystal of anthracene–DTTCNQ" @default.
- W4200623474 cites W1134102491 @default.
- W4200623474 cites W1487696197 @default.
- W4200623474 cites W1974658206 @default.
- W4200623474 cites W1976342669 @default.
- W4200623474 cites W1989955778 @default.
- W4200623474 cites W1990768301 @default.
- W4200623474 cites W1991417000 @default.
- W4200623474 cites W1992708471 @default.
- W4200623474 cites W1995787123 @default.
- W4200623474 cites W2006224207 @default.
- W4200623474 cites W2006370092 @default.
- W4200623474 cites W2008843219 @default.
- W4200623474 cites W2011740029 @default.
- W4200623474 cites W2012001611 @default.
- W4200623474 cites W2014304532 @default.
- W4200623474 cites W2016062805 @default.
- W4200623474 cites W2017936560 @default.
- W4200623474 cites W2026308514 @default.
- W4200623474 cites W2030605900 @default.
- W4200623474 cites W2065224987 @default.
- W4200623474 cites W2069119855 @default.
- W4200623474 cites W2069597072 @default.
- W4200623474 cites W2081668938 @default.
- W4200623474 cites W2087260065 @default.
- W4200623474 cites W2090084145 @default.
- W4200623474 cites W2094133588 @default.
- W4200623474 cites W2100072407 @default.
- W4200623474 cites W2108025345 @default.
- W4200623474 cites W2108161694 @default.
- W4200623474 cites W2114448626 @default.
- W4200623474 cites W2114585259 @default.
- W4200623474 cites W2131381944 @default.
- W4200623474 cites W2132452593 @default.
- W4200623474 cites W2132525235 @default.
- W4200623474 cites W2147156872 @default.
- W4200623474 cites W2152102402 @default.
- W4200623474 cites W2167499408 @default.
- W4200623474 cites W2168039830 @default.
- W4200623474 cites W2168728301 @default.
- W4200623474 cites W2171841005 @default.
- W4200623474 cites W2216963208 @default.
- W4200623474 cites W2286576343 @default.
- W4200623474 cites W2291162614 @default.
- W4200623474 cites W2309760649 @default.
- W4200623474 cites W2312828018 @default.
- W4200623474 cites W2314997890 @default.
- W4200623474 cites W2317821468 @default.
- W4200623474 cites W2317951414 @default.
- W4200623474 cites W2318723788 @default.
- W4200623474 cites W2319100777 @default.
- W4200623474 cites W2321407555 @default.
- W4200623474 cites W2321434108 @default.
- W4200623474 cites W2332995085 @default.
- W4200623474 cites W2337829366 @default.
- W4200623474 cites W2409234725 @default.
- W4200623474 cites W2467822012 @default.
- W4200623474 cites W2472679524 @default.
- W4200623474 cites W2508844932 @default.
- W4200623474 cites W2515739070 @default.
- W4200623474 cites W2520524362 @default.
- W4200623474 cites W2522559948 @default.
- W4200623474 cites W2530112242 @default.
- W4200623474 cites W2560319792 @default.
- W4200623474 cites W2583187016 @default.
- W4200623474 cites W2588940791 @default.
- W4200623474 cites W2624900231 @default.
- W4200623474 cites W2738432880 @default.
- W4200623474 cites W2744865060 @default.
- W4200623474 cites W2770866911 @default.
- W4200623474 cites W2772037893 @default.
- W4200623474 cites W2782684326 @default.
- W4200623474 cites W2785040354 @default.
- W4200623474 cites W2786287726 @default.
- W4200623474 cites W2790408837 @default.
- W4200623474 cites W2792107473 @default.
- W4200623474 cites W2792145561 @default.
- W4200623474 cites W2796480957 @default.
- W4200623474 cites W2801121244 @default.
- W4200623474 cites W2802931319 @default.
- W4200623474 cites W2804269670 @default.
- W4200623474 cites W2837454752 @default.
- W4200623474 cites W2885595351 @default.
- W4200623474 cites W2892702366 @default.
- W4200623474 cites W2899781070 @default.
- W4200623474 cites W2907149813 @default.