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• W4200626412 startingPage "18243" @default.
• W4200626412 abstract "The present study assessed the kinetics of methane reforming with CO2 over a Ni (10%)/La–Al2O3 bimodal pore catalyst. The prepared catalysts showed sustainable activity during a long-term activity study for 100 h at 750 °C and 1 bar. The catalyst was characterized using various analytical techniques to understand the correlation between the catalyst’s physicochemical properties and activity and stability. The kinetic data were collected in a temperature range of 550–650 °C with a step increase of 50 °C at atmospheric pressure. A Langmuir–Hinshelwood–Hougen–Watson (LHHW) model was established by assuming that the CH4 dissociative adsorption and intermediate carbon gasification is the rate-determining step. The developed kinetic expressions satisfactorily fit the experimental data, with an R2 value above 0.95. The apparent activation energies were also calculated." @default.
• W4200626412 created "2021-12-31" @default.
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• W4200626412 date "2021-12-08" @default.
• W4200626412 modified "2023-10-10" @default.
• W4200626412 title "Experimental and Kinetic Studies of Methane Reforming with CO₂ over a La-Doped Ni/Al₂O₃ Bimodal Catalyst" @default.
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• W4200626412 doi "https://doi.org/10.1021/acs.iecr.1c02037" @default.
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