Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205087264> ?p ?o ?g. }
- W4205087264 endingPage "1384" @default.
- W4205087264 startingPage "1376" @default.
- W4205087264 abstract "Broadband near-infrared (NIR) light sources based on phosphor-converted light-emitting diodes (pc-LEDs) are desirable for biochemical analysis and medical diagnosis applications; however, the development of target NIR phosphor is still a challenge. Herein, broadband NIR phosphors, Cr3+-activated CaSc1–xAl1+xSiO6 (λem = 950 nm), are designed and optimized by chemical substitution toward enhanced quantum efficiency and thermal stability. Structural and spectral analyses along with density functional theory calculations reveal that Sc3+/Al3+ substitution contributes to enhancing the structural rigidity and the local symmetry of the [Sc/AlO6] octahedron so that the nonradiative relaxation of Cr3+ emission centers is suppressed significantly. The as-fabricated phosphor-in-glass-based NIR LED light source demonstrates great potential in the detection of alcohol concentration. This study provides a local structure design principle for exploring NIR phosphors with enhanced thermal stability and will also stimulate further studies on material discovery and quantitative analysis of NIR spectroscopy." @default.
- W4205087264 created "2022-01-25" @default.
- W4205087264 creator A5019995449 @default.
- W4205087264 creator A5070426045 @default.
- W4205087264 creator A5081962415 @default.
- W4205087264 date "2022-01-19" @default.
- W4205087264 modified "2023-10-14" @default.
- W4205087264 title "Structural Rigidity Control toward Cr<sup>3+</sup>-Based Broadband Near-Infrared Luminescence with Enhanced Thermal Stability" @default.
- W4205087264 cites W1965793782 @default.
- W4205087264 cites W2014405789 @default.
- W4205087264 cites W2021126689 @default.
- W4205087264 cites W2049528955 @default.
- W4205087264 cites W2054316210 @default.
- W4205087264 cites W2080380365 @default.
- W4205087264 cites W2085765714 @default.
- W4205087264 cites W2093298507 @default.
- W4205087264 cites W2137211437 @default.
- W4205087264 cites W2154306928 @default.
- W4205087264 cites W2160211341 @default.
- W4205087264 cites W2167590372 @default.
- W4205087264 cites W2743942944 @default.
- W4205087264 cites W2794985145 @default.
- W4205087264 cites W2807616496 @default.
- W4205087264 cites W2892309889 @default.
- W4205087264 cites W2895816821 @default.
- W4205087264 cites W2897119344 @default.
- W4205087264 cites W2899835796 @default.
- W4205087264 cites W2911971298 @default.
- W4205087264 cites W2936515329 @default.
- W4205087264 cites W2946866287 @default.
- W4205087264 cites W2956099959 @default.
- W4205087264 cites W2976097294 @default.
- W4205087264 cites W2979777375 @default.
- W4205087264 cites W2980208179 @default.
- W4205087264 cites W2981216692 @default.
- W4205087264 cites W2981292320 @default.
- W4205087264 cites W2990857153 @default.
- W4205087264 cites W2992280135 @default.
- W4205087264 cites W3008181067 @default.
- W4205087264 cites W3018807270 @default.
- W4205087264 cites W3019172017 @default.
- W4205087264 cites W3025029753 @default.
- W4205087264 cites W3033540132 @default.
- W4205087264 cites W3037820384 @default.
- W4205087264 cites W3082100301 @default.
- W4205087264 cites W3087680290 @default.
- W4205087264 cites W3112367749 @default.
- W4205087264 cites W3125556143 @default.
- W4205087264 cites W3134363557 @default.
- W4205087264 cites W3134397967 @default.
- W4205087264 cites W3136962650 @default.
- W4205087264 cites W3137542235 @default.
- W4205087264 cites W3140229933 @default.
- W4205087264 cites W3141569264 @default.
- W4205087264 cites W3156575331 @default.
- W4205087264 cites W3165720761 @default.
- W4205087264 cites W3171611468 @default.
- W4205087264 cites W3173215106 @default.
- W4205087264 cites W3173260308 @default.
- W4205087264 cites W3180883317 @default.
- W4205087264 cites W3194199766 @default.
- W4205087264 cites W3205828238 @default.
- W4205087264 cites W3207900057 @default.
- W4205087264 cites W3208985053 @default.
- W4205087264 cites W4205167145 @default.
- W4205087264 doi "https://doi.org/10.1021/acs.chemmater.1c04131" @default.
- W4205087264 hasPublicationYear "2022" @default.
- W4205087264 type Work @default.
- W4205087264 citedByCount "69" @default.
- W4205087264 countsByYear W42050872642022 @default.
- W4205087264 countsByYear W42050872642023 @default.
- W4205087264 crossrefType "journal-article" @default.
- W4205087264 hasAuthorship W4205087264A5019995449 @default.
- W4205087264 hasAuthorship W4205087264A5070426045 @default.
- W4205087264 hasAuthorship W4205087264A5081962415 @default.
- W4205087264 hasConcept C120665830 @default.
- W4205087264 hasConcept C121332964 @default.
- W4205087264 hasConcept C148869448 @default.
- W4205087264 hasConcept C158355884 @default.
- W4205087264 hasConcept C159985019 @default.
- W4205087264 hasConcept C160343418 @default.
- W4205087264 hasConcept C171250308 @default.
- W4205087264 hasConcept C178790620 @default.
- W4205087264 hasConcept C185592680 @default.
- W4205087264 hasConcept C192562407 @default.
- W4205087264 hasConcept C204530211 @default.
- W4205087264 hasConcept C49040817 @default.
- W4205087264 hasConcept C509933004 @default.
- W4205087264 hasConcept C59061564 @default.
- W4205087264 hasConcept C97355855 @default.
- W4205087264 hasConceptScore W4205087264C120665830 @default.
- W4205087264 hasConceptScore W4205087264C121332964 @default.
- W4205087264 hasConceptScore W4205087264C148869448 @default.
- W4205087264 hasConceptScore W4205087264C158355884 @default.
- W4205087264 hasConceptScore W4205087264C159985019 @default.
- W4205087264 hasConceptScore W4205087264C160343418 @default.
- W4205087264 hasConceptScore W4205087264C171250308 @default.
- W4205087264 hasConceptScore W4205087264C178790620 @default.