Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205122815> ?p ?o ?g. }
- W4205122815 endingPage "128299" @default.
- W4205122815 startingPage "128299" @default.
- W4205122815 abstract "Metal-organic frameworks (MOFs) have attracted more attention because of their excellent environmental catalytic capabilities. Modulation approach as an advanced assistant strategy is vital essential to enhancing the performance of MOFs. In this study, the modulated method was used to successfully synthesize a group of Fe-based MOFs, with formic acid as the modulator on the synthesis mixture. The most modulated sample Fe-MOFs-2 exhibit high specific surface areas and higher catalytic activity, which could effectively degrade SMX via PS activation, with almost 95% removal efficiency within 120 min. The results revealed that the % RSE of modulated Fe-MOFs-2 increased from 2.31 to 3.27 when compared with the origin Fe-MOFs. This may be due to the addition of formic acid induces the formation of more coordinatively unsaturated metal sites in the catalyst, resulting in structural defects. In addition, the quenching experiment and EPR analysis verified SO4-·and·OH as the major active free radicals in the degradation process. Modulated Fe-MOFs-2 demonstrated good reusability and stability under fifth cycles. Finally, four possible degradation pathways and catalytic mechanism of Fe-MOFs-2 was tentatively proposed. Our work provides insights into the rational design of modulated Fe-MOFs as promising heterogeneous catalysts for advanced wastewater treatment." @default.
- W4205122815 created "2022-01-25" @default.
- W4205122815 creator A5002869474 @default.
- W4205122815 creator A5003642180 @default.
- W4205122815 creator A5004047914 @default.
- W4205122815 creator A5024778291 @default.
- W4205122815 creator A5042788485 @default.
- W4205122815 creator A5047360429 @default.
- W4205122815 creator A5053935179 @default.
- W4205122815 creator A5059085639 @default.
- W4205122815 date "2022-05-01" @default.
- W4205122815 modified "2023-10-17" @default.
- W4205122815 title "Modulated construction of Fe-based MOF via formic acid modulator for enhanced degradation of sulfamethoxazole：Design, degradation pathways, and mechanism" @default.
- W4205122815 cites W1260788982 @default.
- W4205122815 cites W1940506446 @default.
- W4205122815 cites W1967984071 @default.
- W4205122815 cites W1993633382 @default.
- W4205122815 cites W2041911040 @default.
- W4205122815 cites W2095016950 @default.
- W4205122815 cites W2102548965 @default.
- W4205122815 cites W2119504742 @default.
- W4205122815 cites W2218991269 @default.
- W4205122815 cites W2293816320 @default.
- W4205122815 cites W2300158998 @default.
- W4205122815 cites W2301635874 @default.
- W4205122815 cites W2328967289 @default.
- W4205122815 cites W2333547949 @default.
- W4205122815 cites W2337685078 @default.
- W4205122815 cites W2343782327 @default.
- W4205122815 cites W2403406451 @default.
- W4205122815 cites W2419604106 @default.
- W4205122815 cites W2543940523 @default.
- W4205122815 cites W2546728141 @default.
- W4205122815 cites W2551371417 @default.
- W4205122815 cites W2588011371 @default.
- W4205122815 cites W2591822179 @default.
- W4205122815 cites W2593379385 @default.
- W4205122815 cites W2593730372 @default.
- W4205122815 cites W2603445336 @default.
- W4205122815 cites W2604084092 @default.
- W4205122815 cites W2604148523 @default.
- W4205122815 cites W2618127528 @default.
- W4205122815 cites W2639803253 @default.
- W4205122815 cites W2739423301 @default.
- W4205122815 cites W2754238021 @default.
- W4205122815 cites W2767642191 @default.
- W4205122815 cites W2792892989 @default.
- W4205122815 cites W2794376292 @default.
- W4205122815 cites W2796009291 @default.
- W4205122815 cites W2799316305 @default.
- W4205122815 cites W2807144966 @default.
- W4205122815 cites W2807533776 @default.
- W4205122815 cites W2809217155 @default.
- W4205122815 cites W2811411974 @default.
- W4205122815 cites W2841606001 @default.
- W4205122815 cites W2864570211 @default.
- W4205122815 cites W2898648420 @default.
- W4205122815 cites W2913309373 @default.
- W4205122815 cites W2922211844 @default.
- W4205122815 cites W2944245584 @default.
- W4205122815 cites W2947153096 @default.
- W4205122815 cites W2980798313 @default.
- W4205122815 cites W2980963435 @default.
- W4205122815 cites W2997359723 @default.
- W4205122815 cites W2998960409 @default.
- W4205122815 cites W3015716307 @default.
- W4205122815 cites W3016254271 @default.
- W4205122815 cites W3030524849 @default.
- W4205122815 cites W3031615809 @default.
- W4205122815 cites W3049263184 @default.
- W4205122815 cites W3061649818 @default.
- W4205122815 cites W3093908899 @default.
- W4205122815 cites W3153480860 @default.
- W4205122815 cites W376699256 @default.
- W4205122815 cites W947192931 @default.
- W4205122815 doi "https://doi.org/10.1016/j.jhazmat.2022.128299" @default.
- W4205122815 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35077971" @default.
- W4205122815 hasPublicationYear "2022" @default.
- W4205122815 type Work @default.
- W4205122815 citedByCount "47" @default.
- W4205122815 countsByYear W42051228152022 @default.
- W4205122815 countsByYear W42051228152023 @default.
- W4205122815 crossrefType "journal-article" @default.
- W4205122815 hasAuthorship W4205122815A5002869474 @default.
- W4205122815 hasAuthorship W4205122815A5003642180 @default.
- W4205122815 hasAuthorship W4205122815A5004047914 @default.
- W4205122815 hasAuthorship W4205122815A5024778291 @default.
- W4205122815 hasAuthorship W4205122815A5042788485 @default.
- W4205122815 hasAuthorship W4205122815A5047360429 @default.
- W4205122815 hasAuthorship W4205122815A5053935179 @default.
- W4205122815 hasAuthorship W4205122815A5059085639 @default.
- W4205122815 hasConcept C121332964 @default.
- W4205122815 hasConcept C121745418 @default.
- W4205122815 hasConcept C127413603 @default.
- W4205122815 hasConcept C129652920 @default.
- W4205122815 hasConcept C137981799 @default.
- W4205122815 hasConcept C150394285 @default.
- W4205122815 hasConcept C161790260 @default.