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• W4205123024 abstract "It is very interesting to synthesize high value-added chemicals from CO2 under mild conditions with low energy consumption. Here, we report that a novel catalyst, Zn(betaine)2Br2, can efficiently promote the cycloaddition of CO2 with epoxides to synthesize cyclic carbonates under ambient conditions (30 °C, 1 atm). DFT calculations provide important insights into the mechanism, particularly the unusual synergistic catalytic action of Zn2+, Br- and NR4+, which is the critical factor for the outstanding performance of Zn(betaine)2Br2. The unique features of the catalyst are that it is cheap, green and very easy to prepare." @default.
• W4205123024 created "2022-01-26" @default.
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• W4205123024 date "2022-01-01" @default.
• W4205123024 modified "2023-10-12" @default.
• W4205123024 title "Efficient synthesis of cyclic carbonates from CO₂ under ambient conditions over Zn(betaine)₂Br₂: experimental and theoretical studies" @default.
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• W4205123024 doi "https://doi.org/10.1039/d1cp05553d" @default.
• W4205123024 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35107469" @default.
• W4205123024 hasPublicationYear "2022" @default.
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