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- W4205123533 abstract "The reaction of tetradentate azomethine ligands H2salen* [N,N′-ethylenebis(2–hydroxyacetophenoneimine)] or Hzsalen* [N,N′-ethylene-bis(3,5–di-tert-butyl-sali-cylideneimine)] with chlorosilanes produces silicon compounds with hexacoordinated silicon (salen)SiXY (X = Cl; Y = H, Cl, C, C6H5). Both ligands X and Y can be exchanged for fluorine. The crystal structure analysis of (salen*)SiF2 reveals the truly hexacoordination of the silicon atom. The chloro compounds (salen*)SiCl2 undergo Wurtz-type coupling reactions leading to oligosilanes with hypervalent silicon. Coupling of (salen*)SiCl2 with acetylides creates compounds with an Si-CEC-Si backbone." @default.
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- W4205123533 date "2005-07-26" @default.
- W4205123533 modified "2023-10-03" @default.
- W4205123533 title "Salen‐Silicon Complexes — a New Type of Hexacoordinate Silicon" @default.
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- W4205123533 doi "https://doi.org/10.1002/9783527620777.ch85c" @default.
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