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- W4205251210 abstract "This chapter discusses the theoretical aspects, synthesis, and properties of isoindoles. Isoindole and its analogs––isobenzofuran and isothianaphthene have attracted considerable theoretical and synthetic interest. The chemistry of isoindoles and with isoindolenines, where there is the possibility of tautomerism with, or rearrangement to, the isoindole system is reviewed. Whether isoindole possesses aromatic stabilization in excess of that exhibited by pyrrole is also explored. Several calculations of the electronic structure of isoindoles and the distribution of charge density around the isoindole nucleus calculated by LCAO-MO method or frontier electron concept are tabulated. The properties of the isoindole system includes: (1) tautomerism, (2) electrophillic substitution, (3) reduction–oxidation, (4) diels–alder addition, and (5) spectroscopic properties. Isoindolines comprise a group of well–characterized and easily synthesized substances, and constitute suitable precursors for synthesis of the isoindoles. The synthesis of isoindoles is usually carried by: the syntheses from isoindolines, phthalimidines, ortho–disubstituted benzenes, and condensation of 1, 4–diketones with amines and pyrroles. Some other rearrangements and reactions leading to synthesis of isoindoles are also discussed." @default.
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- W4205251210 date "1969-01-01" @default.
- W4205251210 modified "2023-09-23" @default.
- W4205251210 title "Isoindoles" @default.
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- W4205251210 doi "https://doi.org/10.1016/s0065-2725(08)60496-1" @default.
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