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• W4205258214 abstract "Der (cAAC)2Mn-Komplex (cAAC=cyclisches Alkyl(amino)carben) enthält ein lineares zweifach koordiniertes Mn-Zentrum. Die antiferromagnetische Wechselwirkung eines ungepaarten Elektrons, das zwischen den zwei Carben-C-Atomen delokalisiert ist, mit dem zentralen MnI, das eine d6-Konfiguration hat, trägt hauptsächlich zum ST=3/2-Grundzustand bei. Die Behandlung von (cAAC)2Mn mit H2 bei Raumtemperatur führt zur Addition der H-Atome an beide Carben-C-Atome, wonach für das zentrale Mn-Atom ein ST=5/2-Grundzustand resultiert." @default.
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• W4205258214 date "2013-09-13" @default.
• W4205258214 modified "2023-10-06" @default.
• W4205258214 title "Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature" @default.
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• W4205258214 doi "https://doi.org/10.1002/ange.201304642" @default.
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