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- W4205380028 abstract "Dideutero-methane 12CH2D2 is unique among all the methane isotopomers because of its asymmetric-top nature. Here, we first report the fine ro-vibrational gas-phase spectra of 12CH2D2 isotopomer in the a-type ν9 (B2-symmetry) fundamental band near 7.8 µm using ultra-sensitive cavity ring-down spectroscopy (CRDS) instrument in the mid-infrared spectral region. We utilized Gaussian 16 to calculate the relevant spectroscopic parameters of 12CH2D2 and subsequently performed the PGOPHER simulation for precise assignments of the fine ro-vibrational lines of 12CH2D2. Further, we conducted the pressure broadening dynamics of 12CH2D2 isotopomer with various foreign gases and accurately determined the pressure broadening coefficients, γi in cm−1 atm−1 [i = He, Ar, N2, Hydrogen mixture(H2 + N2) and zero air] of various transition lines of 12CH2D2." @default.
- W4205380028 created "2022-01-25" @default.
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- W4205380028 date "2022-02-01" @default.
- W4205380028 modified "2023-10-18" @default.
- W4205380028 title "Ro-vibrational spectral features and pressure broadening dynamics of dideutero-methane (12CH2D2) in the ν9(B2) fundamental band" @default.
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- W4205380028 doi "https://doi.org/10.1016/j.jms.2022.111572" @default.
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