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- W4205384476 abstract "A Pd-catalyzed cascade C-H functionalization/asymmetric allylation reaction with aryl α-diazoamides and allenes has been developed. The reaction provides an efficient approach to construct chiral 3,3-disubstituted oxindole derivatives in high levels of yield and enantioselectivity (up to 93 % ee). Notably, the chromium complex works as Lewis acid to facilitate the formation of palladium carbene and to enhance acidity of carboxylic acid, allowing for higher stereochemical control and efficiency." @default.
- W4205384476 created "2022-01-26" @default.
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- W4205384476 date "2022-01-28" @default.
- W4205384476 modified "2023-10-17" @default.
- W4205384476 title "Palladium‐Catalyzed Cascade C−H Functionalization/Asymmetric Allylation Reaction of Aryl α‐Diazoamides and Allenes: Lewis Acid Makes a Difference" @default.
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- W4205384476 doi "https://doi.org/10.1002/chem.202104218" @default.
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