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- W4205440782 abstract "In this paper, [email protected]/C composites have been prepared by solvothermal process, mechanical blending and subsequent calcination under N2. The composites were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electrons microscopy and transmission electron microscopy. The contributions of TiN to the electrochemical properties of [email protected]/C composites were further discussed by changing its relative contents in composites, respectively. The results indicate that cycling stability and high-rate property of [email protected]/C composites are improved with the increasing of TiN content. The obtained [email protected](1:0.5)/C composites deliver a capacity retentions of 82.3% after 100 cycles at 0.5 A·g−1 and 74.3% after 200 cycles at 1 A·g−1. Moreover, their specific capacities can still reach 710 mAh·g−1 even at 8 A·g−1. The excellent electrochemical performances of [email protected]/C composites should be attributed to the synergistic effect of TiN and C in composites, which makes the buffering matrix around Si particles have high conductivity and mechanical stability." @default.
- W4205440782 created "2022-01-25" @default.
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- W4205440782 date "2022-02-01" @default.
- W4205440782 modified "2023-09-23" @default.
- W4205440782 title "Contribution of TiN to the enhanced cycling stability of Si@TiN/C composites as anode materials for Li-ion batteries" @default.
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- W4205440782 doi "https://doi.org/10.1016/j.jelechem.2022.116010" @default.
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