Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205601392> ?p ?o ?g. }
- W4205601392 endingPage "1873" @default.
- W4205601392 startingPage "1866" @default.
- W4205601392 abstract "KBiNb2O7 was prepared from RbBiNb2O7 by a sequence of cation exchange reactions which first convert RbBiNb2O7 to LiBiNb2O7, before KBiNb2O7 is formed by a further K-for-Li cation exchange. A combination of neutron, synchrotron X-ray and electron diffraction data reveal that KBiNb2O7 adopts a polar, layered, perovskite structure (space group A11m) in which the BiNb2O7 layers are stacked in a (0, ½, z) arrangement, with the K+ cations located in half of the available 10-coordinate interlayer cation sites. The inversion symmetry of the phase is broken by a large displacement of the Bi3+ cations parallel to the y-axis. HAADF-STEM images reveal that KBiNb2O7 exhibits frequent stacking faults which convert the (0, ½, z) layer stacking to (½, 0, z) stacking and vice versa, essentially switching the x- and y-axes of the material. By fitting the complex diffraction peak shape of the SXRD data collected from KBiNb2O7 it is estimated that each layer has approximately a 9% chance of being defective - a high level which is attributed to the lack of cooperative NbO6 tilting in the material, which limits the lattice strain associated with each fault." @default.
- W4205601392 created "2022-01-25" @default.
- W4205601392 creator A5003373881 @default.
- W4205601392 creator A5006652779 @default.
- W4205601392 creator A5008107880 @default.
- W4205601392 creator A5033140792 @default.
- W4205601392 creator A5039044513 @default.
- W4205601392 creator A5057651510 @default.
- W4205601392 creator A5077785194 @default.
- W4205601392 date "2022-01-01" @default.
- W4205601392 modified "2023-09-28" @default.
- W4205601392 title "The crystal and defect structures of polar KBiNb2O7" @default.
- W4205601392 cites W1649612108 @default.
- W4205601392 cites W1981026770 @default.
- W4205601392 cites W1986703897 @default.
- W4205601392 cites W1993995478 @default.
- W4205601392 cites W1994255850 @default.
- W4205601392 cites W2003779791 @default.
- W4205601392 cites W2004669139 @default.
- W4205601392 cites W2007045586 @default.
- W4205601392 cites W2017699992 @default.
- W4205601392 cites W2021426961 @default.
- W4205601392 cites W2026130269 @default.
- W4205601392 cites W2036508048 @default.
- W4205601392 cites W2042719212 @default.
- W4205601392 cites W2047548160 @default.
- W4205601392 cites W2057459010 @default.
- W4205601392 cites W2069421401 @default.
- W4205601392 cites W2074019256 @default.
- W4205601392 cites W2075860386 @default.
- W4205601392 cites W2087670974 @default.
- W4205601392 cites W2101453822 @default.
- W4205601392 cites W2101741054 @default.
- W4205601392 cites W2315213081 @default.
- W4205601392 cites W2334843210 @default.
- W4205601392 cites W2763873175 @default.
- W4205601392 cites W2805114272 @default.
- W4205601392 cites W2868971002 @default.
- W4205601392 cites W2897949003 @default.
- W4205601392 cites W2903461203 @default.
- W4205601392 cites W3017845899 @default.
- W4205601392 cites W3081395763 @default.
- W4205601392 cites W3103439873 @default.
- W4205601392 cites W3149147971 @default.
- W4205601392 cites W3202691522 @default.
- W4205601392 cites W71105945 @default.
- W4205601392 doi "https://doi.org/10.1039/d1dt04064b" @default.
- W4205601392 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35018920" @default.
- W4205601392 hasPublicationYear "2022" @default.
- W4205601392 type Work @default.
- W4205601392 citedByCount "0" @default.
- W4205601392 crossrefType "journal-article" @default.
- W4205601392 hasAuthorship W4205601392A5003373881 @default.
- W4205601392 hasAuthorship W4205601392A5006652779 @default.
- W4205601392 hasAuthorship W4205601392A5008107880 @default.
- W4205601392 hasAuthorship W4205601392A5033140792 @default.
- W4205601392 hasAuthorship W4205601392A5039044513 @default.
- W4205601392 hasAuthorship W4205601392A5057651510 @default.
- W4205601392 hasAuthorship W4205601392A5077785194 @default.
- W4205601392 hasBestOaLocation W42056013921 @default.
- W4205601392 hasConcept C115624301 @default.
- W4205601392 hasConcept C120665830 @default.
- W4205601392 hasConcept C121332964 @default.
- W4205601392 hasConcept C1276947 @default.
- W4205601392 hasConcept C155011858 @default.
- W4205601392 hasConcept C176932811 @default.
- W4205601392 hasConcept C178790620 @default.
- W4205601392 hasConcept C185592680 @default.
- W4205601392 hasConcept C188914724 @default.
- W4205601392 hasConcept C192562407 @default.
- W4205601392 hasConcept C207114421 @default.
- W4205601392 hasConcept C21368211 @default.
- W4205601392 hasConcept C24890656 @default.
- W4205601392 hasConcept C26873012 @default.
- W4205601392 hasConcept C2778536302 @default.
- W4205601392 hasConcept C2781204021 @default.
- W4205601392 hasConcept C29705727 @default.
- W4205601392 hasConcept C33347731 @default.
- W4205601392 hasConcept C50515024 @default.
- W4205601392 hasConcept C73585123 @default.
- W4205601392 hasConcept C77557913 @default.
- W4205601392 hasConcept C8010536 @default.
- W4205601392 hasConceptScore W4205601392C115624301 @default.
- W4205601392 hasConceptScore W4205601392C120665830 @default.
- W4205601392 hasConceptScore W4205601392C121332964 @default.
- W4205601392 hasConceptScore W4205601392C1276947 @default.
- W4205601392 hasConceptScore W4205601392C155011858 @default.
- W4205601392 hasConceptScore W4205601392C176932811 @default.
- W4205601392 hasConceptScore W4205601392C178790620 @default.
- W4205601392 hasConceptScore W4205601392C185592680 @default.
- W4205601392 hasConceptScore W4205601392C188914724 @default.
- W4205601392 hasConceptScore W4205601392C192562407 @default.
- W4205601392 hasConceptScore W4205601392C207114421 @default.
- W4205601392 hasConceptScore W4205601392C21368211 @default.
- W4205601392 hasConceptScore W4205601392C24890656 @default.
- W4205601392 hasConceptScore W4205601392C26873012 @default.
- W4205601392 hasConceptScore W4205601392C2778536302 @default.
- W4205601392 hasConceptScore W4205601392C2781204021 @default.