FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205615769> ?p ?o ?g. }

• W4205615769 abstract "Abstract Binary lithium silicides and germanides as well as ternary lithium phosphidotetrelates have been intensively investigated with regard to their suitability as anode materials for all‐solid‐state‐batteries. In this context we studied the ternary phase diagram Li/ Tt /P on the phosphorus‐poor side. The phosphide tetrelides Li 10.68(8) Si 5 P and Li 10.1(2) Ge 5 P are ternary compounds in the respective phase systems so far uniquely featuring discrete building blocks, which were previously found exclusively in binary alkali metal tetrelides and phosphides. Li 10.68(8) Si 5 P and Li 10.1(2) Ge 5 P contain aromatic Tt 5 pentagons with an environment of mostly ordered Li atoms and isolated P 3− anions with a coordination environment of predominantly disordered Li atoms. The five‐membered ring subunits are stacked under formation of [Li 6 Tt 5 ] chains ( Tt =Si, Ge). chains. The compounds crystallize in the space group Pnma (63) ( Z =4) with cell parameters of a =10.2434(3) Å, b =4.2788(1) Å, c =23.9767(3) Å for Li 10.68(8) Si 5 P and a =10.3599(11) Å, b =4.3072(2) Å, c =24.267(2) Å for Li 10.1(2) Ge 5 P. The single crystal structure determination is supplemented by X‐ray powder diffraction experiments and 7 Li, 29 Si and 31 P solid state MAS NMR spectroscopy. With respect to their electron count the compounds are placed between compounds comprising aromatic five‐membered rings such as the electron‐precise Zintl phase Li 8 MgSi 6 and the non‐classical Zintl phase Li 12 Si 7 having two extra electrons." @default.
• W4205615769 created "2022-01-25" @default.
• W4205615769 creator A5001481242 @default.
• W4205615769 creator A5007240588 @default.
• W4205615769 creator A5033103828 @default.
• W4205615769 creator A5036437226 @default.
• W4205615769 creator A5050325128 @default.
• W4205615769 date "2022-01-31" @default.
• W4205615769 modified "2023-09-27" @default.
• W4205615769 title "Planar Si5 and Ge5 Pentagons beside Isolated Phosphide Anions in Lithium Phosphide Tetrelides Li10+xSi5P and Li10+xGe5P" @default.
• W4205615769 cites W1540946498 @default.
• W4205615769 cites W1915187664 @default.
• W4205615769 cites W1967697636 @default.
• W4205615769 cites W1969360633 @default.
• W4205615769 cites W1974018524 @default.
• W4205615769 cites W1978176236 @default.
• W4205615769 cites W1998500289 @default.
• W4205615769 cites W1998981899 @default.
• W4205615769 cites W2005646961 @default.
• W4205615769 cites W2016730434 @default.
• W4205615769 cites W2025398697 @default.
• W4205615769 cites W2038564064 @default.
• W4205615769 cites W2046764154 @default.
• W4205615769 cites W2053126449 @default.
• W4205615769 cites W2073887259 @default.
• W4205615769 cites W2127856528 @default.
• W4205615769 cites W2133991199 @default.
• W4205615769 cites W2136829520 @default.
• W4205615769 cites W2147786599 @default.
• W4205615769 cites W2151407652 @default.
• W4205615769 cites W2197550433 @default.
• W4205615769 cites W2325768445 @default.
• W4205615769 cites W2331597208 @default.
• W4205615769 cites W2413067157 @default.
• W4205615769 cites W2524792448 @default.
• W4205615769 cites W2543900264 @default.
• W4205615769 cites W2550613263 @default.
• W4205615769 cites W2617127851 @default.
• W4205615769 cites W2789291459 @default.
• W4205615769 cites W2808260231 @default.
• W4205615769 cites W2862306811 @default.
• W4205615769 cites W2888494000 @default.
• W4205615769 cites W2896828275 @default.
• W4205615769 cites W2920688008 @default.
• W4205615769 cites W2949225398 @default.
• W4205615769 cites W2951109628 @default.
• W4205615769 cites W2951763282 @default.
• W4205615769 cites W2968058512 @default.
• W4205615769 cites W2990697693 @default.
• W4205615769 cites W3005233177 @default.
• W4205615769 cites W3044036960 @default.
• W4205615769 cites W3105248494 @default.
• W4205615769 cites W3167677706 @default.
• W4205615769 doi "https://doi.org/10.1002/zaac.202100376" @default.
• W4205615769 hasPublicationYear "2022" @default.
• W4205615769 type Work @default.
• W4205615769 citedByCount "0" @default.
• W4205615769 crossrefType "journal-article" @default.
• W4205615769 hasAuthorship W4205615769A5001481242 @default.
• W4205615769 hasAuthorship W4205615769A5007240588 @default.
• W4205615769 hasAuthorship W4205615769A5033103828 @default.
• W4205615769 hasAuthorship W4205615769A5036437226 @default.
• W4205615769 hasAuthorship W4205615769A5050325128 @default.
• W4205615769 hasBestOaLocation W42056157691 @default.
• W4205615769 hasConcept C115624301 @default.
• W4205615769 hasConcept C121332964 @default.
• W4205615769 hasConcept C134018914 @default.
• W4205615769 hasConcept C147120987 @default.
• W4205615769 hasConcept C151730666 @default.
• W4205615769 hasConcept C178790620 @default.
• W4205615769 hasConcept C185592680 @default.
• W4205615769 hasConcept C192562407 @default.
• W4205615769 hasConcept C198091228 @default.
• W4205615769 hasConcept C199360897 @default.
• W4205615769 hasConcept C2778541603 @default.
• W4205615769 hasConcept C2779343474 @default.
• W4205615769 hasConcept C2780654602 @default.
• W4205615769 hasConcept C2780740876 @default.
• W4205615769 hasConcept C41008148 @default.
• W4205615769 hasConcept C544153396 @default.
• W4205615769 hasConcept C62520636 @default.
• W4205615769 hasConcept C64452783 @default.
• W4205615769 hasConcept C71924100 @default.
• W4205615769 hasConcept C8010536 @default.
• W4205615769 hasConcept C86803240 @default.
• W4205615769 hasConceptScore W4205615769C115624301 @default.
• W4205615769 hasConceptScore W4205615769C121332964 @default.
• W4205615769 hasConceptScore W4205615769C134018914 @default.
• W4205615769 hasConceptScore W4205615769C147120987 @default.
• W4205615769 hasConceptScore W4205615769C151730666 @default.
• W4205615769 hasConceptScore W4205615769C178790620 @default.
• W4205615769 hasConceptScore W4205615769C185592680 @default.
• W4205615769 hasConceptScore W4205615769C192562407 @default.
• W4205615769 hasConceptScore W4205615769C198091228 @default.
• W4205615769 hasConceptScore W4205615769C199360897 @default.
• W4205615769 hasConceptScore W4205615769C2778541603 @default.
• W4205615769 hasConceptScore W4205615769C2779343474 @default.
• W4205615769 hasConceptScore W4205615769C2780654602 @default.
• W4205615769 hasConceptScore W4205615769C2780740876 @default.
• W4205615769 hasConceptScore W4205615769C41008148 @default.

• next