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- W4205636694 endingPage "831" @default.
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- W4205636694 abstract "We disclose a Ag-catalyzed asymmetric interrupted Barton-Zard reaction of α-aryl-substituted isocyanoacetates with 2- and 3-nitroindoles, which enables the dearomatization of nitroindoles and hence offers rapid access to an array of optically active tetrahydropyrrolo[3,4-b]indole derivatives bearing three contiguous stereogenic centers, including two tetrasubstituted chiral carbon atoms with pretty outcomes (up to 99% yield, 91:9 dr, and 96% ee). The synthetic potential of the protocol was showcased by the gram-scale reaction and versatile transformations of the product." @default.
- W4205636694 created "2022-01-26" @default.
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- W4205636694 date "2022-01-14" @default.
- W4205636694 modified "2023-10-14" @default.
- W4205636694 title "Ag-Catalyzed Asymmetric Interrupted Barton–Zard Reaction Enabling the Enantioselective Dearomatization of 2- and 3-Nitroindoles" @default.
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- W4205636694 doi "https://doi.org/10.1021/acs.orglett.1c04036" @default.
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