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• W4205653330 endingPage "1274" @default.
• W4205653330 startingPage "1270" @default.
• W4205653330 abstract "11-Azido-9,10-dihydro-9,10-phosphanoanthracene (N3PA) has been demonstrated recently as a transfer reagent for molecular phosphorus mononitride (PN) because it easily dissociates at room temperature into dinitrogen (N2), PN, and anthracene (A). Here we report further reactivity studies of the N3PA molecule including strain-promoted 1,3-dipolar cycloaddition with cyclooctyne and Staudinger-type reactivity. Calculations at the DLPNO-CCSD(T)/cc-pVTZ//PBE0-D3(BJ)/cc-pVTZ level of theory indicate that the click reaction is faster than the dissociation of N3PA. The Staudinger-type reactivity enabled transfer of the NPA fragment to a base-stabilized silylene. The previously reported intermediate of vanadium trisanilide with an NPA ligand could be isolated in 61% yield and structurally characterized in a single-crystal X-ray diffraction experiment. In line with the previously reported phosphinidene reactivity of the transient vanadium phosphorus mononitride complex, thermolysis or irradiation of the complex leads to A elimination and formation of the corresponding vanadium PN dimer or trimer, respectively." @default.
• W4205653330 created "2022-01-26" @default.
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• W4205653330 date "2022-01-12" @default.
• W4205653330 modified "2023-10-16" @default.
• W4205653330 title "Staudinger Reactivity and Click Chemistry of Anthracene (<b>A</b>)-Based Azidophosphine N₃P<b>A</b>" @default.
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• W4205653330 doi "https://doi.org/10.1021/acs.inorgchem.1c03753" @default.
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