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- W4205653590 abstract "A 'principles and practice' tutorial-style review of the application of solution-phase NMR in the analysis of the mechanisms of homogeneous organic and organometallic reactions and processes. This review of 345 references summarises why solution-phase NMR spectroscopy is uniquely effective in such studies, allowing non-destructive, quantitative analysis of a wide range of nuclei common to organic and organometallic reactions, providing exquisite structural detail, and using instrumentation that is routinely available in most chemistry research facilities. The review is in two parts. The first comprises an introduction to general techniques and equipment, and guidelines for their selection and application. Topics include practical aspects of the reaction itself, reaction monitoring techniques, NMR data acquisition and processing, analysis of temporal concentration data, NMR titrations, DOSY, and the use of isotopes. The second part comprises a series of 15 Case Studies, each selected to illustrate specific techniques and approaches discussed in the first part, including in situ NMR (1/2H, 10/11B, 13C, 15N, 19F, 29Si, 31P), kinetic and equilibrium isotope effects, isotope entrainment, isotope shifts, isotopes at natural abundance, scalar coupling, kinetic analysis (VTNA, RPKA, simulation, steady-state), stopped-flow NMR, flow NMR, rapid injection NMR, pure shift NMR, dynamic nuclear polarisation, 1H/19F DOSY NMR, and in situ illumination NMR." @default.
- W4205653590 created "2022-01-25" @default.
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- W4205653590 date "2022-04-01" @default.
- W4205653590 modified "2023-10-16" @default.
- W4205653590 title "Mechanistic analysis by NMR spectroscopy: A users guide" @default.
- W4205653590 cites W147746416 @default.
- W4205653590 cites W1482715598 @default.
- W4205653590 cites W1483538456 @default.
- W4205653590 cites W1498651264 @default.
- W4205653590 cites W1501993347 @default.
- W4205653590 cites W1580392549 @default.
- W4205653590 cites W1775896041 @default.
- W4205653590 cites W1826494397 @default.
- W4205653590 cites W1869042642 @default.
- W4205653590 cites W1919674992 @default.
- W4205653590 cites W1940548232 @default.
- W4205653590 cites W1964850371 @default.
- W4205653590 cites W1968153979 @default.
- W4205653590 cites W1969527028 @default.
- W4205653590 cites W1970121803 @default.
- W4205653590 cites W1972352407 @default.
- W4205653590 cites W1974707312 @default.
- W4205653590 cites W1975122842 @default.
- W4205653590 cites W1975125132 @default.
- W4205653590 cites W1977934683 @default.
- W4205653590 cites W1978272160 @default.
- W4205653590 cites W1979259658 @default.
- W4205653590 cites W1981627552 @default.
- W4205653590 cites W1982691491 @default.
- W4205653590 cites W1984857202 @default.
- W4205653590 cites W1985121507 @default.
- W4205653590 cites W1988326881 @default.
- W4205653590 cites W1988963221 @default.
- W4205653590 cites W1989648819 @default.
- W4205653590 cites W1989818941 @default.
- W4205653590 cites W1990844998 @default.
- W4205653590 cites W1991651763 @default.
- W4205653590 cites W1991763410 @default.
- W4205653590 cites W1993602486 @default.
- W4205653590 cites W1995552771 @default.
- W4205653590 cites W1995987437 @default.
- W4205653590 cites W1996222877 @default.
- W4205653590 cites W1996273492 @default.
- W4205653590 cites W1996456502 @default.
- W4205653590 cites W1996759270 @default.
- W4205653590 cites W1997343663 @default.
- W4205653590 cites W1997727558 @default.
- W4205653590 cites W1998206608 @default.
- W4205653590 cites W1998892260 @default.
- W4205653590 cites W1999178195 @default.
- W4205653590 cites W1999471365 @default.
- W4205653590 cites W1999581086 @default.
- W4205653590 cites W2004227499 @default.
- W4205653590 cites W2004650212 @default.
- W4205653590 cites W2005692644 @default.
- W4205653590 cites W2008453360 @default.
- W4205653590 cites W2010969835 @default.
- W4205653590 cites W2013592470 @default.
- W4205653590 cites W2014552314 @default.
- W4205653590 cites W2015718732 @default.
- W4205653590 cites W2016210486 @default.
- W4205653590 cites W2016860713 @default.
- W4205653590 cites W2017697943 @default.
- W4205653590 cites W2020996271 @default.
- W4205653590 cites W2022216240 @default.
- W4205653590 cites W2024590395 @default.
- W4205653590 cites W2024755622 @default.
- W4205653590 cites W2026388793 @default.
- W4205653590 cites W2028028087 @default.
- W4205653590 cites W2029077477 @default.
- W4205653590 cites W2030112310 @default.
- W4205653590 cites W2030841140 @default.
- W4205653590 cites W2031046599 @default.
- W4205653590 cites W2032114611 @default.
- W4205653590 cites W2032480466 @default.
- W4205653590 cites W2032572844 @default.
- W4205653590 cites W2033552143 @default.
- W4205653590 cites W2033942748 @default.
- W4205653590 cites W2034753666 @default.
- W4205653590 cites W2035447400 @default.
- W4205653590 cites W2035832119 @default.
- W4205653590 cites W2035865284 @default.
- W4205653590 cites W2036937609 @default.
- W4205653590 cites W2038164161 @default.
- W4205653590 cites W2039737278 @default.