Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205656613> ?p ?o ?g. }
- W4205656613 endingPage "8" @default.
- W4205656613 startingPage "1" @default.
- W4205656613 abstract "• Selectively regulating PDS-to-∙OH conversion was achieved over irradiated MIL-100(Fe). • CUSs and coordinated H 2 O played pivotal roles in PDS-to-∙OH conversion. • The mechanism of PDS-to-∙OH conversion over irradiated MIL-100(Fe) was investigated. • PDS/MIL-100(Fe) exhibited high stability and reusability for pollutant degradation. Selective regulation of peroxydisulfate (PDS) activation-to-hydroxyl radical (·OH) production (PDS-to-·OH) is important for in situ chemical oxidation. However, the regulation mechanisms still lack reasonable explorations. Herein, a novel system involving the selective regulation of PDS-to-·OH was investigated using Fe-based metal-organic frameworks (MOF; MIL-100(Fe)) under visible light irradiation. Spectroscopic characterizations and controlled experiments indicated that the PDS chemically linked between coordinatively unsaturated metal sites (CUSs) and coordinated H 2 O in MIL-100(Fe) plays critical role in regulating the PDS-to-·OH transformation. Consequently, the constructed PDS/MIL-100(Fe) system showed improved performance not only in the organic degradation rate but also in PDS utilization efficiency compared with that of the traditional sulfate radical (SO 4 · - )-mediated PDS/MIL-68(Fe) system. This work provides new insights into the regulation of PDS activation to ·OH generation over heterogeneous catalysis. Moreover, considering the diverse compositions and structures of MOFs, this work also demonstrates their feasibility as efficient light-induced materials for in situ chemical oxidation." @default.
- W4205656613 created "2022-01-26" @default.
- W4205656613 creator A5013444004 @default.
- W4205656613 creator A5022309473 @default.
- W4205656613 creator A5023960601 @default.
- W4205656613 creator A5068602599 @default.
- W4205656613 creator A5076397371 @default.
- W4205656613 creator A5082581372 @default.
- W4205656613 creator A5082986078 @default.
- W4205656613 creator A5090385327 @default.
- W4205656613 date "2022-02-01" @default.
- W4205656613 modified "2023-10-02" @default.
- W4205656613 title "Selective regulation of peroxydisulfate-to-hydroxyl radical for efficient in-situ chemical oxidation over Fe-based metal-organic frameworks under visible light" @default.
- W4205656613 cites W2004666790 @default.
- W4205656613 cites W2019635083 @default.
- W4205656613 cites W2027470555 @default.
- W4205656613 cites W2032578873 @default.
- W4205656613 cites W2040667521 @default.
- W4205656613 cites W2140356073 @default.
- W4205656613 cites W2322118693 @default.
- W4205656613 cites W2485842556 @default.
- W4205656613 cites W2583126019 @default.
- W4205656613 cites W2586783714 @default.
- W4205656613 cites W2604531885 @default.
- W4205656613 cites W2761466767 @default.
- W4205656613 cites W2770125280 @default.
- W4205656613 cites W2787909461 @default.
- W4205656613 cites W2791958841 @default.
- W4205656613 cites W2796009291 @default.
- W4205656613 cites W2797914563 @default.
- W4205656613 cites W2888827392 @default.
- W4205656613 cites W2899066373 @default.
- W4205656613 cites W2911583999 @default.
- W4205656613 cites W2922395279 @default.
- W4205656613 cites W2924925172 @default.
- W4205656613 cites W2980370912 @default.
- W4205656613 cites W2986676376 @default.
- W4205656613 cites W2997136793 @default.
- W4205656613 cites W2999844418 @default.
- W4205656613 cites W3005285218 @default.
- W4205656613 cites W3009319290 @default.
- W4205656613 cites W3017101350 @default.
- W4205656613 cites W3023124676 @default.
- W4205656613 cites W3047153142 @default.
- W4205656613 cites W3084200785 @default.
- W4205656613 cites W3103093243 @default.
- W4205656613 cites W3103154373 @default.
- W4205656613 cites W3138034884 @default.
- W4205656613 cites W3150211751 @default.
- W4205656613 cites W3163299845 @default.
- W4205656613 cites W3188981101 @default.
- W4205656613 cites W3200104281 @default.
- W4205656613 cites W2896545321 @default.
- W4205656613 doi "https://doi.org/10.1016/j.jcat.2021.12.027" @default.
- W4205656613 hasPublicationYear "2022" @default.
- W4205656613 type Work @default.
- W4205656613 citedByCount "9" @default.
- W4205656613 countsByYear W42056566132022 @default.
- W4205656613 countsByYear W42056566132023 @default.
- W4205656613 crossrefType "journal-article" @default.
- W4205656613 hasAuthorship W4205656613A5013444004 @default.
- W4205656613 hasAuthorship W4205656613A5022309473 @default.
- W4205656613 hasAuthorship W4205656613A5023960601 @default.
- W4205656613 hasAuthorship W4205656613A5068602599 @default.
- W4205656613 hasAuthorship W4205656613A5076397371 @default.
- W4205656613 hasAuthorship W4205656613A5082581372 @default.
- W4205656613 hasAuthorship W4205656613A5082986078 @default.
- W4205656613 hasAuthorship W4205656613A5090385327 @default.
- W4205656613 hasConcept C111337013 @default.
- W4205656613 hasConcept C121332964 @default.
- W4205656613 hasConcept C137981799 @default.
- W4205656613 hasConcept C139066938 @default.
- W4205656613 hasConcept C150394285 @default.
- W4205656613 hasConcept C161790260 @default.
- W4205656613 hasConcept C178790620 @default.
- W4205656613 hasConcept C179104552 @default.
- W4205656613 hasConcept C179366358 @default.
- W4205656613 hasConcept C185544564 @default.
- W4205656613 hasConcept C185592680 @default.
- W4205656613 hasConcept C199360897 @default.
- W4205656613 hasConcept C2776778087 @default.
- W4205656613 hasConcept C2777904410 @default.
- W4205656613 hasConcept C2779679103 @default.
- W4205656613 hasConcept C2780192469 @default.
- W4205656613 hasConcept C41008148 @default.
- W4205656613 hasConcept C544153396 @default.
- W4205656613 hasConcept C65165184 @default.
- W4205656613 hasConcept C75473681 @default.
- W4205656613 hasConcept C76155785 @default.
- W4205656613 hasConceptScore W4205656613C111337013 @default.
- W4205656613 hasConceptScore W4205656613C121332964 @default.
- W4205656613 hasConceptScore W4205656613C137981799 @default.
- W4205656613 hasConceptScore W4205656613C139066938 @default.
- W4205656613 hasConceptScore W4205656613C150394285 @default.
- W4205656613 hasConceptScore W4205656613C161790260 @default.
- W4205656613 hasConceptScore W4205656613C178790620 @default.
- W4205656613 hasConceptScore W4205656613C179104552 @default.
- W4205656613 hasConceptScore W4205656613C179366358 @default.