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- W4205694103 abstract "Publisher SummaryThis chapter discusses ligand coupling involving other heteroatoms. It focuses on the chemistry of organoantimony, organoselenium, organotellurium, and organothallium compounds. The application of organoantimony compounds to synthetic organic chemistry has been increasing. In spite of the relatively weak energy of the antimony-element bond, compared to the analogous phosphorus compounds for example, the reactions of ligand transfer with organoantimony are scarce. Among these reactions, only a limited number of ligand coupling reactions have been reported with different pentavalent antimony compounds. Under organoselenium, the chapter discusses reactions of arylselenium compounds, alkylselenium compounds, perfluoroselenonium salts, and benzeneseleninic anhydride. Organotellurium involves various types of mechanistic pathways, such as ionic, radical, or intramolecular rearrangements. The ligand coupling mechanism has also been invoked to explain a series of transformation." @default.
- W4205694103 created "2022-01-25" @default.
- W4205694103 date "1998-01-01" @default.
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- W4205694103 title "Chapter 8 Ligand Coupling involving other heteroatoms" @default.
- W4205694103 doi "https://doi.org/10.1016/s1460-1567(98)80023-8" @default.
- W4205694103 hasPublicationYear "1998" @default.
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