FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205787911> ?p ?o ?g. }

• W4205787911 endingPage "1671" @default.
• W4205787911 startingPage "1661" @default.
• W4205787911 abstract "The ultrahigh stability of the ferrocene@cucurbit[7]uril (Fc@CB[7]) host–guest inclusion complex enables its promising application as a novel immobilization/conjugation motif for constructing biosensors and molecular devices. However, its supramolecular complexation on surface has been rarely studied, which is partially due to the limited success of current CB[7] immobilization strategies (suffering from either poor stability or inconvenient and time-consuming procedures). In this work, we have successfully tethered alkyne-functionalized CB[7] (≡-O-CB[7]) on azide-terminated self-assembled monolayers (SAMs) on gold via the copper(I)-catalyzed azide–alkyne cycloaddition reaction with high efficiency. With this new approach, highly stable and uniform CB[7]-functionalized SAMs were obtained, which enabled us to gain insights into the recognition properties of CB[7] toward various Fc derivatives on the surface. In particular, the derived complexation thermodynamic (e.g., for FcMeOH, Kf = (1.6 ± 0.3) × 107 M–1) and kinetic (ka = (2.6 ± 0.4) × 103 M–1 s–1, kd = (5.1 ± 0.3) × 10–5 s–1) data indicate the strong interfacial host–guest binding of surface-bound CB[7] toward both cationic and neutral ferrocene derivatives. Remarkably, a comparable binding stability was observed for the anionic ferrocene derivative with an increased distance between the ferrocene core and negatively charged substituent, which is significant for immobilizing/conjugating negatively charged biological macromolecules (e.g., DNA probes)." @default.
• W4205787911 created "2022-01-26" @default.
• W4205787911 creator A5006080491 @default.
• W4205787911 creator A5027416136 @default.
• W4205787911 creator A5028734301 @default.
• W4205787911 creator A5033323748 @default.
• W4205787911 creator A5061130250 @default.
• W4205787911 date "2022-01-18" @default.
• W4205787911 modified "2023-10-05" @default.
• W4205787911 title "“Click” Cucurbit[7]uril Hosts on Self-Assembled Monolayers: Quantitative Supramolecular Complexation with Ferrocene Guests" @default.
• W4205787911 cites W1781421830 @default.
• W4205787911 cites W1820204933 @default.
• W4205787911 cites W1964803346 @default.
• W4205787911 cites W1972194130 @default.
• W4205787911 cites W1976212255 @default.
• W4205787911 cites W1981804877 @default.
• W4205787911 cites W1986374446 @default.
• W4205787911 cites W1991094247 @default.
• W4205787911 cites W1993336787 @default.
• W4205787911 cites W1994384674 @default.
• W4205787911 cites W1998855337 @default.
• W4205787911 cites W2007692747 @default.
• W4205787911 cites W2008348255 @default.
• W4205787911 cites W2013000841 @default.
• W4205787911 cites W2015001791 @default.
• W4205787911 cites W2016384435 @default.
• W4205787911 cites W2029663014 @default.
• W4205787911 cites W2044578454 @default.
• W4205787911 cites W2053749115 @default.
• W4205787911 cites W2069805392 @default.
• W4205787911 cites W2076004018 @default.
• W4205787911 cites W2077534391 @default.
• W4205787911 cites W2080558515 @default.
• W4205787911 cites W2082063506 @default.
• W4205787911 cites W2086380577 @default.
• W4205787911 cites W2088396668 @default.
• W4205787911 cites W2093498573 @default.
• W4205787911 cites W2100951800 @default.
• W4205787911 cites W2102495865 @default.
• W4205787911 cites W2107834451 @default.
• W4205787911 cites W2112552355 @default.
• W4205787911 cites W2137834621 @default.
• W4205787911 cites W2138699357 @default.
• W4205787911 cites W2145662716 @default.
• W4205787911 cites W2152380893 @default.
• W4205787911 cites W2253050824 @default.
• W4205787911 cites W2313612068 @default.
• W4205787911 cites W2314501155 @default.
• W4205787911 cites W2317136863 @default.
• W4205787911 cites W2343970701 @default.
• W4205787911 cites W2423163451 @default.
• W4205787911 cites W2496092469 @default.
• W4205787911 cites W2497513363 @default.
• W4205787911 cites W2546622582 @default.
• W4205787911 cites W2599436986 @default.
• W4205787911 cites W2791040222 @default.
• W4205787911 cites W2809722643 @default.
• W4205787911 cites W2945864397 @default.
• W4205787911 cites W2954943833 @default.
• W4205787911 cites W3017020298 @default.
• W4205787911 cites W3047486707 @default.
• W4205787911 cites W3158027777 @default.
• W4205787911 cites W3162934442 @default.
• W4205787911 cites W4254720078 @default.
• W4205787911 doi "https://doi.org/10.1021/acs.jpcc.1c09781" @default.
• W4205787911 hasPublicationYear "2022" @default.
• W4205787911 type Work @default.
• W4205787911 citedByCount "3" @default.
• W4205787911 countsByYear W42057879112022 @default.
• W4205787911 countsByYear W42057879112023 @default.
• W4205787911 crossrefType "journal-article" @default.
• W4205787911 hasAuthorship W4205787911A5006080491 @default.
• W4205787911 hasAuthorship W4205787911A5027416136 @default.
• W4205787911 hasAuthorship W4205787911A5028734301 @default.
• W4205787911 hasAuthorship W4205787911A5033323748 @default.
• W4205787911 hasAuthorship W4205787911A5061130250 @default.
• W4205787911 hasConcept C147789679 @default.
• W4205787911 hasConcept C161790260 @default.
• W4205787911 hasConcept C17525397 @default.
• W4205787911 hasConcept C178790620 @default.
• W4205787911 hasConcept C183882617 @default.
• W4205787911 hasConcept C185592680 @default.
• W4205787911 hasConcept C188027245 @default.
• W4205787911 hasConcept C21951064 @default.
• W4205787911 hasConcept C2777237805 @default.
• W4205787911 hasConcept C2778689049 @default.
• W4205787911 hasConcept C2779012754 @default.
• W4205787911 hasConcept C2779664164 @default.
• W4205787911 hasConcept C2780997848 @default.
• W4205787911 hasConcept C32909587 @default.
• W4205787911 hasConcept C52859227 @default.
• W4205787911 hasConcept C55493867 @default.
• W4205787911 hasConcept C69610077 @default.
• W4205787911 hasConcept C7070889 @default.
• W4205787911 hasConcept C71240020 @default.
• W4205787911 hasConcept C75473681 @default.
• W4205787911 hasConcept C83263248 @default.
• W4205787911 hasConcept C83730648 @default.

• next