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• W4205841668 abstract "A series of triplet 9-triptycyl(aryl)carbenes, where aryl groups are phenyl, 1- and 2-naphthyl, and 9-anthryl, is generated by photolysis of the corresponding diazomethanes and observed directly by spectroscopic means. Their structures are characterized by electron spin resonance (ESR) spectroscopy in a 2-methyltetrahydrofuran matrix at 77 K, and the reactivities are investigated by laser flash photolysis in degassed benzene solution at room temperature. Comparison of the data with other arylcarbenes bearing a series of substituents, i.e., hydrogen, phenyl, naphthyl, and anthryl groups, revealed an interesting relationship between structures and reactivities of triplet arylcarbenes.Key words: steric protection, stability of triplet carbenes, electron spin resonance, laser flash photolysis, structure-reactivity relationship." @default.
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• W4205841668 date "1999-06-01" @default.
• W4205841668 modified "2023-10-02" @default.
• W4205841668 title "Article" @default.
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• W4205841668 doi "https://doi.org/10.1139/v99-092" @default.
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