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• W4205850600 endingPage "13430" @default.
• W4205850600 startingPage "13420" @default.
• W4205850600 abstract "Treatment of waste water via photocatalysis is one of the most effective, economical and environment friendly process. In this study, green method (leaf extract of Citrus Medica Linn.) is used to synthesize pure and lanthanum (La)-(1,2 & 3 wt%) doped copper oxide nanoparticles (CuO-NPs). Different characterization techniques such as XRD, SEM, EDS, UV/VIS, PL and FTIR are utilized to investigate their physical, chemical, optical and structural properties. The synthesized material is used as photocatalyst for degradation of methylene blue (MB) dye. Interestingly, the La doped CuO-NPs have exhibited unique results. Variation in dopant concentration reduces the particle size (40.82 ± 0.04 nm to 31.89 ± 0.02 nm) and band gap of material shifts towards visible region (3.03 eV–2.71 eV). During photocatalysis, doping reduces the electron-hole pair recombination rate which makes it a potential photocatalyst. Maximum degradation efficiency of 84% is observed in 150 min for 2% La doped CuO-NPs which reveals that 2% La doping is optimal. Further increase in dopant concentration increases band gap, therefore, degradation efficiency drops to 75%. Simulation of this work is carried out using COMSOL Multiphysics 5.3a Licensed version. A 2D model is constructed and CuO-NPs is considered as photocatalyst in order to correlate simulated and experimental photocatalytic degradation of MB and rhodamine B (RhB) dye. Comparative analysis of rate constants revealed that the trend given by simulation is very close to the experimental observations." @default.
• W4205850600 created "2022-01-25" @default.
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• W4205850600 date "2022-05-01" @default.
• W4205850600 modified "2023-10-16" @default.
• W4205850600 title "Green synthesis of novel lanthanum doped copper oxide nanoparticles for photocatalytic application: Correlation between experiment and COMSOL simulation" @default.
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• W4205850600 doi "https://doi.org/10.1016/j.ceramint.2022.01.160" @default.
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