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- W4205865487 abstract "In order to improve the efficiency and stability of inverted three-dimensional (3D) or quasi-2D perovskite solar cells (PSCs) for future commercialization, exploring high efficient dopant-free polymer hole-transporting materials (HTMs) is still desired and meaningful. One simple and efficient way to achieve high performance dopant-free HTMs is to synthesize novel non-conjugated side-chain polymers via rational molecular design. In this work, N-(4-methoxyphenyl)-9,9-dimethyl-9H-fluoren-2-amine (FMeNPh) groups are introduced into the poly(N-vinylcarbazole) (PVK) side chains to afford two non-conjugated polymers PVCz-DFMeNPh and PVCz-FMeNPh as dopant-free HTMs in inverted quasi-2D PSCs. Benefited from the flexible properties of polyethylene backbone and excellent optoelectronic natures of FMeNPh side-chain groups, PVCz-DFMeNPh with more FMeNPh units exhibited excellent thermal stability, well-matched energy levels and improved charge mobility as compared to PTAA and PVCz-FMeNPh. Moreover, the morphologies investigation of quasi-2D perovskite on PVCz-DFMeNPh shows more compact and homogeneous perovskite films than those on PTAA and PVCz-FMeNPh. As a result, the dopant-free PVCz-DFMeNPh based inverted quasi-2D PSCs deliver power conversion efficiency (PCE) up to 18.44% as well as negligible hysteresis and favorable long-term stability, which represents as excellent performance reported to date for inverted quasi-2D PSCs. The results demonstrate the great potentials of constructing non-conjugated side-chain polymer HTMs based on phenylfluorenamine-functionalized PVK for the development of high efficient and stable inverted 3D or quasi-2D PSCs." @default.
- W4205865487 created "2022-01-26" @default.
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- W4205865487 date "2022-06-01" @default.
- W4205865487 modified "2023-10-06" @default.
- W4205865487 title "Phenylfluorenamine-functionalized poly(N-vinylcarbazole)s as dopant-free polymer hole-transporting materials for inverted quasi-2D perovskite solar cells" @default.
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- W4205865487 doi "https://doi.org/10.1016/j.jechem.2022.01.013" @default.
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