FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4205963516> ?p ?o ?g. }

• W4205963516 abstract "Abstract A phase diagram is a graphical object, usually determined experimentally, indicating phase relationships in thermodynamic space. Usually, one coordinate axis represents temperature; the others may represent pressure, volume, concentrations of various components, and so on. This unit is concerned only with temperature‐concentration diagrams, limited to binary (two‐component) and ternary (three‐component) systems. Since more than one component is considered, the relevant thermodynamic systems are alloys, by definition, of metallic, ceramic, or semiconductor materials. The emphasis here is placed primarily on metallic alloys. Phase diagrams can be classified broadly into two main categories: experimentally and theoretically determined. The object of the present unit is the theoretical determination—i.e., the calculation of phase diagrams, meaning ultimately their prediction. But calculation of phase diagrams can mean different things: there are prototype, fitted, and first‐principles approaches. Prototype diagrams are calculated under the assumption that energy parameters are known a priori or given arbitrarily. Fitted diagrams are those whose energy parameters are fitted to known, experimentally determined diagrams or to empirical thermodynamic data. First‐principles diagrams are calculated on the basis of energy parameters calculated from essentially only the knowledge of the atomic numbers of the constituents, hence by actually solving the relevant Schrödinger equation. Theory also enters in the experimental determination of phase diagrams, as these diagrams not only indicate the location in thermodynamic space of existing phases but also must conform to rigorous rules of thermodynamic equilibrium (stable or metastable). The fundamental rule of equality of chemical potentials imposes severe constraints on the graphical representation of phase diagrams, while also permitting an extraordinary variety of forms and shapes of phase diagrams to exist, even for binary systems. That is one of the attractions of the study of phase diagrams, experimental or theoretical: their great topological diversity subject to strict thermodynamic constraints. In addition, phase diagrams provide essential information for the understanding and designing of materials, and so are of vital importance to materials scientists. For theoreticians, first‐principles (or ab initio ) calculations of phase diagrams provide enormous challenges, requiring the use of advanced techniques of quantum and statistical mechanics." @default.
• W4205963516 created "2022-01-26" @default.
• W4205963516 creator A5054645896 @default.
• W4205963516 date "2002-10-15" @default.
• W4205963516 modified "2023-10-09" @default.
• W4205963516 title "Prediction of Phase Diagrams" @default.
• W4205963516 cites W1484557230 @default.
• W4205963516 cites W1566393914 @default.
• W4205963516 cites W1665572606 @default.
• W4205963516 cites W172329400 @default.
• W4205963516 cites W1772299910 @default.
• W4205963516 cites W1965257437 @default.
• W4205963516 cites W1966861503 @default.
• W4205963516 cites W1968917670 @default.
• W4205963516 cites W1970019666 @default.
• W4205963516 cites W1972499735 @default.
• W4205963516 cites W1973563034 @default.
• W4205963516 cites W1976454075 @default.
• W4205963516 cites W1978891517 @default.
• W4205963516 cites W1979837402 @default.
• W4205963516 cites W1981766923 @default.
• W4205963516 cites W1984000621 @default.
• W4205963516 cites W1987593739 @default.
• W4205963516 cites W1991902636 @default.
• W4205963516 cites W1992318377 @default.
• W4205963516 cites W1994319606 @default.
• W4205963516 cites W1994600848 @default.
• W4205963516 cites W1995397222 @default.
• W4205963516 cites W1997787300 @default.
• W4205963516 cites W2006370926 @default.
• W4205963516 cites W2006910868 @default.
• W4205963516 cites W2007995670 @default.
• W4205963516 cites W2009426984 @default.
• W4205963516 cites W2011681275 @default.
• W4205963516 cites W2013836931 @default.
• W4205963516 cites W2015671424 @default.
• W4205963516 cites W2017451520 @default.
• W4205963516 cites W2017524615 @default.
• W4205963516 cites W2019052821 @default.
• W4205963516 cites W2021887715 @default.
• W4205963516 cites W2024339474 @default.
• W4205963516 cites W2025623427 @default.
• W4205963516 cites W2026024951 @default.
• W4205963516 cites W2028145536 @default.
• W4205963516 cites W2033247236 @default.
• W4205963516 cites W2033514379 @default.
• W4205963516 cites W2033597945 @default.
• W4205963516 cites W2036705900 @default.
• W4205963516 cites W2040977489 @default.
• W4205963516 cites W2045843416 @default.
• W4205963516 cites W2046505730 @default.
• W4205963516 cites W2046928344 @default.
• W4205963516 cites W2049166629 @default.
• W4205963516 cites W2049725929 @default.
• W4205963516 cites W2050954762 @default.
• W4205963516 cites W2050986526 @default.
• W4205963516 cites W2054731579 @default.
• W4205963516 cites W2057602097 @default.
• W4205963516 cites W2065591495 @default.
• W4205963516 cites W2066162751 @default.
• W4205963516 cites W2066571785 @default.
• W4205963516 cites W2067668135 @default.
• W4205963516 cites W2068561951 @default.
• W4205963516 cites W2069483681 @default.
• W4205963516 cites W2071072542 @default.
• W4205963516 cites W2073608393 @default.
• W4205963516 cites W2077136899 @default.
• W4205963516 cites W2077602936 @default.
• W4205963516 cites W2078536172 @default.
• W4205963516 cites W2080101986 @default.
• W4205963516 cites W2088550677 @default.
• W4205963516 cites W2091542196 @default.
• W4205963516 cites W2097479736 @default.
• W4205963516 cites W2116493763 @default.
• W4205963516 cites W2220735130 @default.
• W4205963516 cites W2324693212 @default.
• W4205963516 cites W2328572646 @default.
• W4205963516 cites W2331575658 @default.
• W4205963516 cites W4231655782 @default.
• W4205963516 doi "https://doi.org/10.1002/0471266965.com011" @default.
• W4205963516 hasPublicationYear "2002" @default.
• W4205963516 type Work @default.
• W4205963516 citedByCount "0" @default.
• W4205963516 crossrefType "other" @default.
• W4205963516 hasAuthorship W4205963516A5054645896 @default.
• W4205963516 hasConcept C105795698 @default.
• W4205963516 hasConcept C111472728 @default.
• W4205963516 hasConcept C121332964 @default.
• W4205963516 hasConcept C121864883 @default.
• W4205963516 hasConcept C12426560 @default.
• W4205963516 hasConcept C138885662 @default.
• W4205963516 hasConcept C14380042 @default.
• W4205963516 hasConcept C145644426 @default.
• W4205963516 hasConcept C168054591 @default.
• W4205963516 hasConcept C168167062 @default.
• W4205963516 hasConcept C186399060 @default.
• W4205963516 hasConcept C199360897 @default.
• W4205963516 hasConcept C202446494 @default.
• W4205963516 hasConcept C2524010 @default.
• W4205963516 hasConcept C2777904410 @default.

• next