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- W4206044186 abstract "A beryllium pressure vessel has been used to investigate the two face-centered phases of cerium at various temperatures and pressures along the phase boundary. X-ray diffraction records of the strong 111 peak of both phases show that the two peaks coalesce with increasing temperature and pressure along the boundary. The P-t region for the critical end point of the boundary is obtained by extrapolation of the change in d-spacing with distance along the boundary, and is found to be 350–400°C and 20–22 kb.The X-ray data also show that the compressibility and thermal expansion of the high-pressure (II) phase are greater than those of the low-pressure (I) phase.Rate studies indicate that under pressure phase I persists into the phase II stability field with lowering temperature. Considerable overstepping of pressure into this field is also possible before complete transformation of I–II will take place." @default.
- W4206044186 created "2022-01-26" @default.
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- W4206044186 date "1963-12-01" @default.
- W4206044186 modified "2023-09-26" @default.
- W4206044186 title "X-ray diffraction evidence for a critical end point for cerium I and cerium II" @default.
- W4206044186 doi "https://doi.org/10.1016/0038-1098(63)90018-8" @default.
- W4206044186 hasPublicationYear "1963" @default.
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