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• W4206049618 abstract "Abstract The antimicrobial, anticancer, and antioxidant activities of four cobalt (III) complexes, [CoL 2 ]X (X = ClO 4 ¯ ( 1 ); OAc¯ ( 2 ), Cl¯ ( 3 ), or NO 3 ¯ ( 4 ) with hydralazine Schiff base derivative ( HL ), were presented. The structure of the newly synthesized complexes 1 and 2 was confirmed utilizing FTIR, UV‐Vis, and NMR ( 1 H and 13 C) spectroscopy. In addition, single crystal X‐ray diffraction was used to approve the structure of complex 1 . Based on Hirshfeld analysis, the molecular packing of 1 is controlled by short HH, OH, NH, and HC(π) interactions. The results of the X‐ray photoelectron spectroscopy ( XPS ) for the Co (III) complexes revealed the characteristic peaks of Co 2p3/2 and Co 2p1/2 with binding energy differences of 14.85 – 14.96 which greatly approved that the Co (III) complexes have been assembled successfully. Complex 4 (IC 50 = 14.97 ± 0.59 μg/ml) has the highest cytotoxicity against lung carcinoma A‐549 cell line compared to the rest of the Co (III) complexes and the free ligand as well. Also, complex 4 has the best antioxidant activity with IC 50 of 283.4 ± 12.3 μg/ml. The free ligand has broad spectrum of antibacterial and antifungal actions, while the studied Co (III) complexes have good antibacterial activity especially the chloride complex 3 ." @default.
• W4206049618 created "2022-01-26" @default.
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• W4206049618 date "2022-01-03" @default.
• W4206049618 modified "2023-10-17" @default.
• W4206049618 title "Synthesis, structure, X‐ray photoelectron spectroscopy (XPS), and antimicrobial, anticancer, and antioxidant activities of Co (III) complexes based on the antihypertensive hydralazine" @default.
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• W4206049618 doi "https://doi.org/10.1002/aoc.6565" @default.
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