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- W4206081833 abstract "The chapter focuses on metal-bearing nanocontainers of different types. First, typical metallosurfactants are discussed, with their synthesis, self-assembling behavior, solubilization properties, and morphological characteristics emphasized. In this section, different metals and ligands are considered, and their influence on aggregation thresholds and structural characteristics is analyzed. These micellar nanocontainers are of particular importance from the viewpoint of biomedical application due to their own antimicrobial properties and therapeutic effects. In addition, the complexation of metallosurfactants with biomolecules is mentioned. Second, development of a conceptually new trend for amphiphilic and supra-amphiphilic system based on metallosurfactants and macrocycles is considered. The design of nanoscale superstructure construction from flexible surfactant molecules and solid macrocycles is being actively developed, but the creation of metallosurfactant/macrocycle compositions has only just begun and limited with few studies. Supramolecular aggregates based on metalloamphiphile–macrocycle complexes have several advantages, such as the simplicity of preparing and further modification with stimulus-sensitive and targeting ligands, and their selective biological activity. Third, catalytically active silver- and palladium-loaded nanocomposites based on amphiphilic resorcinarene macrocycles were developed. For these hybrid supramolecular and polymer nanocontainers, the influence of the morphology and the structure of the organic shell on the stability and catalytic activity are shown." @default.
- W4206081833 created "2022-01-26" @default.
- W4206081833 creator A5000739282 @default.
- W4206081833 creator A5030140325 @default.
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- W4206081833 creator A5071365764 @default.
- W4206081833 creator A5085140054 @default.
- W4206081833 date "2022-01-07" @default.
- W4206081833 modified "2023-10-15" @default.
- W4206081833 title "Supramolecular Metal‐Modified Nanocontainers Based on Amphiphilic and Hybrid Matrix: Self‐Assembling Behavior and Practical Applications" @default.
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