Matches in SemOpenAlex for { <https://semopenalex.org/work/W4206145626> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W4206145626 endingPage "139841" @default.
- W4206145626 startingPage "139841" @default.
- W4206145626 abstract "The electrochemical behavior of 1,4-dinitrobenzene (PNB) in the aprotic solvent containing CO 2 was investigated by using CO 2 instead of proton donor to eliminate the interference of hydrogenation reaction. In the absence of CO 2 , the electrochemical behavior of PNB was a chemical reversible two-steps one-electron transfer process, but with the introduction of CO 2 , it was transformed into an irreversible 7-electrons transfer process. In the potential range between −0.3 V and −1.7 V, three reduction peaks were observed, and minutely studied by cyclic voltammetry, chronoamperometry, and in situ FT-IR spectroelectrochemistry methods, respectively. The results show that CO 2 is involved in five steps reaction during the electroreduction process of PNB, which plays a key role in PNB electroreduction azo coupling. The electroreduction azo coupling mechanism of PNB in the presence of CO 2 is exposed, which will provide a theoretical basis for precise control of the electroreduction degradation of dinitrobenzene. The product obtained by potentiostatic electrolysis is confirmed as 4,4′-dinitrosoazobenzene by 13 C NMR, 1 H NMR, MS and FTIR because of the instability of the final product, which is consistent with the mechanism inference. It has been well-proved that in situ FT-IR spectroelectrochemistry is an applicable method to study the wide range of complex electrochemical process." @default.
- W4206145626 created "2022-01-26" @default.
- W4206145626 creator A5026221722 @default.
- W4206145626 creator A5031526554 @default.
- W4206145626 creator A5046597133 @default.
- W4206145626 creator A5075220339 @default.
- W4206145626 date "2022-02-01" @default.
- W4206145626 modified "2023-09-27" @default.
- W4206145626 title "Investigation on the electroreduction azo coupling mechanism of 1,4-dinitrobenzene in aprotic media containing CO2" @default.
- W4206145626 cites W1063578344 @default.
- W4206145626 cites W1649400226 @default.
- W4206145626 cites W1984030435 @default.
- W4206145626 cites W2010558852 @default.
- W4206145626 cites W2017547006 @default.
- W4206145626 cites W2019773085 @default.
- W4206145626 cites W2028639891 @default.
- W4206145626 cites W2043408927 @default.
- W4206145626 cites W2053249887 @default.
- W4206145626 cites W2067010723 @default.
- W4206145626 cites W2073547484 @default.
- W4206145626 cites W2082254719 @default.
- W4206145626 cites W2084001657 @default.
- W4206145626 cites W2092883505 @default.
- W4206145626 cites W2095434603 @default.
- W4206145626 cites W2101017339 @default.
- W4206145626 cites W2166753372 @default.
- W4206145626 cites W2224046307 @default.
- W4206145626 cites W2290180541 @default.
- W4206145626 cites W2329303392 @default.
- W4206145626 cites W2343738369 @default.
- W4206145626 cites W2529265785 @default.
- W4206145626 cites W2885068829 @default.
- W4206145626 cites W2941846526 @default.
- W4206145626 cites W2945505049 @default.
- W4206145626 cites W2973206487 @default.
- W4206145626 cites W2976948596 @default.
- W4206145626 cites W3186399660 @default.
- W4206145626 cites W3197557483 @default.
- W4206145626 doi "https://doi.org/10.1016/j.electacta.2022.139841" @default.
- W4206145626 hasPublicationYear "2022" @default.
- W4206145626 type Work @default.
- W4206145626 citedByCount "2" @default.
- W4206145626 countsByYear W42061456262022 @default.
- W4206145626 countsByYear W42061456262023 @default.
- W4206145626 crossrefType "journal-article" @default.
- W4206145626 hasAuthorship W4206145626A5026221722 @default.
- W4206145626 hasAuthorship W4206145626A5031526554 @default.
- W4206145626 hasAuthorship W4206145626A5046597133 @default.
- W4206145626 hasAuthorship W4206145626A5075220339 @default.
- W4206145626 hasConcept C121332964 @default.
- W4206145626 hasConcept C131584629 @default.
- W4206145626 hasConcept C147789679 @default.
- W4206145626 hasConcept C17525397 @default.
- W4206145626 hasConcept C179104552 @default.
- W4206145626 hasConcept C185592680 @default.
- W4206145626 hasConcept C188027245 @default.
- W4206145626 hasConcept C191897082 @default.
- W4206145626 hasConcept C192562407 @default.
- W4206145626 hasConcept C2777250486 @default.
- W4206145626 hasConcept C52859227 @default.
- W4206145626 hasConcept C62520636 @default.
- W4206145626 hasConcept C75473681 @default.
- W4206145626 hasConcept C89611455 @default.
- W4206145626 hasConceptScore W4206145626C121332964 @default.
- W4206145626 hasConceptScore W4206145626C131584629 @default.
- W4206145626 hasConceptScore W4206145626C147789679 @default.
- W4206145626 hasConceptScore W4206145626C17525397 @default.
- W4206145626 hasConceptScore W4206145626C179104552 @default.
- W4206145626 hasConceptScore W4206145626C185592680 @default.
- W4206145626 hasConceptScore W4206145626C188027245 @default.
- W4206145626 hasConceptScore W4206145626C191897082 @default.
- W4206145626 hasConceptScore W4206145626C192562407 @default.
- W4206145626 hasConceptScore W4206145626C2777250486 @default.
- W4206145626 hasConceptScore W4206145626C52859227 @default.
- W4206145626 hasConceptScore W4206145626C62520636 @default.
- W4206145626 hasConceptScore W4206145626C75473681 @default.
- W4206145626 hasConceptScore W4206145626C89611455 @default.
- W4206145626 hasLocation W42061456261 @default.
- W4206145626 hasOpenAccess W4206145626 @default.
- W4206145626 hasPrimaryLocation W42061456261 @default.
- W4206145626 hasRelatedWork W1987674700 @default.
- W4206145626 hasRelatedWork W2027602243 @default.
- W4206145626 hasRelatedWork W2086912448 @default.
- W4206145626 hasRelatedWork W2087248011 @default.
- W4206145626 hasRelatedWork W2406618687 @default.
- W4206145626 hasRelatedWork W2771416244 @default.
- W4206145626 hasRelatedWork W2951867754 @default.
- W4206145626 hasRelatedWork W2953250471 @default.
- W4206145626 hasRelatedWork W3137452781 @default.
- W4206145626 hasRelatedWork W780397172 @default.
- W4206145626 hasVolume "406" @default.
- W4206145626 isParatext "false" @default.
- W4206145626 isRetracted "false" @default.
- W4206145626 workType "article" @default.