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- W4206146471 abstract "Catalytic enantioselective access to disubstituted functionalized gem-difluorocyclopropanes, which are emerging fluorinated motifs of interest in medicinal chemistry, was achieved through asymmetric transfer hydrogenation of gem-difluorocyclopropenyl esters, catalyzed by a Noyori–Ikariya (p-cymene)-ruthenium(II) complex, with (N-tosyl-1,2-diphenylethylenediamine) as the chiral ligand and isopropanol as the hydrogen donor. The resulting cis-gem-difluorocyclopropyl esters were obtained with moderate to high enantioselectivity (ee=66–99 %), and post-functionalization reactions enable access to valuable building blocks incorporating a cis- or trans-gem-difluorocyclopropyl motif." @default.
- W4206146471 created "2022-01-25" @default.
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- W4206146471 date "2020-08-25" @default.
- W4206146471 modified "2023-10-13" @default.
- W4206146471 title "Asymmetric Transfer Hydrogenation of <i>gem</i> ‐Difluorocyclopropenyl Esters: Access to Enantioenriched <i>gem</i> ‐Difluorocyclopropanes" @default.
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- W4206146471 doi "https://doi.org/10.1002/anie.202008572" @default.
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