Matches in SemOpenAlex for { <https://semopenalex.org/work/W4206156949> ?p ?o ?g. }
- W4206156949 endingPage "121029" @default.
- W4206156949 startingPage "121029" @default.
- W4206156949 abstract "Alkaline exchange membrane fuel cells are impeded by the lack of cost-effective, highly efficient catalysts for the sluggish hydrogen oxidation reaction (HOR). Herein, single-atomic Pd sites supported by ordered porous N,S-doped carbon are synthesized, exhibiting remarkable alkaline HOR performance. This catalyst exhibits an ultrahigh anodic current density and mass-specific kinetic current of 2.01 mA cm–2 and 27,719 A gPd–1 (at an overpotential of 50 mV), respectively, not only outperforming the Pt/C counterpart but also making it among the best reported HOR catalysts. Furthermore, this catalyst exhibits a negligible activity decay during long-term electrolysis and a good CO tolerance capability. Experiments and theoretical calculations indicate that the synergistic effect from single Pd sites and heteroatom doping (N and S) weakens the binding energy of Had intermediates, thereby accounting for its superior HOR activity. This study provides a guideline for developing single-atomic site catalysts for highly efficient, stable alkaline HOR." @default.
- W4206156949 created "2022-01-25" @default.
- W4206156949 creator A5005398821 @default.
- W4206156949 creator A5006164086 @default.
- W4206156949 creator A5013134790 @default.
- W4206156949 creator A5025324849 @default.
- W4206156949 creator A5035801000 @default.
- W4206156949 creator A5039762889 @default.
- W4206156949 creator A5041521616 @default.
- W4206156949 creator A5042022186 @default.
- W4206156949 creator A5046111523 @default.
- W4206156949 creator A5051812556 @default.
- W4206156949 creator A5059698647 @default.
- W4206156949 creator A5067268817 @default.
- W4206156949 creator A5073300113 @default.
- W4206156949 date "2022-06-01" @default.
- W4206156949 modified "2023-10-09" @default.
- W4206156949 title "Single palladium site in ordered porous heteroatom-doped carbon for high-performance alkaline hydrogen oxidation" @default.
- W4206156949 cites W1168565912 @default.
- W4206156949 cites W1985938896 @default.
- W4206156949 cites W1991149034 @default.
- W4206156949 cites W2028238701 @default.
- W4206156949 cites W2029286928 @default.
- W4206156949 cites W2042488345 @default.
- W4206156949 cites W2043121446 @default.
- W4206156949 cites W2116243685 @default.
- W4206156949 cites W2186286364 @default.
- W4206156949 cites W2236902553 @default.
- W4206156949 cites W2282371201 @default.
- W4206156949 cites W2297431660 @default.
- W4206156949 cites W2306757740 @default.
- W4206156949 cites W2328928309 @default.
- W4206156949 cites W2335695111 @default.
- W4206156949 cites W2396013816 @default.
- W4206156949 cites W2520275386 @default.
- W4206156949 cites W2558739653 @default.
- W4206156949 cites W2580271879 @default.
- W4206156949 cites W2603625925 @default.
- W4206156949 cites W2742693693 @default.
- W4206156949 cites W2772676667 @default.
- W4206156949 cites W2776687276 @default.
- W4206156949 cites W2802475501 @default.
- W4206156949 cites W2803427589 @default.
- W4206156949 cites W2808967607 @default.
- W4206156949 cites W2885901182 @default.
- W4206156949 cites W2886411269 @default.
- W4206156949 cites W2888936985 @default.
- W4206156949 cites W2889012410 @default.
- W4206156949 cites W2889689514 @default.
- W4206156949 cites W2902902027 @default.
- W4206156949 cites W2903807505 @default.
- W4206156949 cites W2907290988 @default.
- W4206156949 cites W2908162069 @default.
- W4206156949 cites W2909267103 @default.
- W4206156949 cites W2910274140 @default.
- W4206156949 cites W2913075899 @default.
- W4206156949 cites W2921821926 @default.
- W4206156949 cites W2934086670 @default.
- W4206156949 cites W2942845693 @default.
- W4206156949 cites W2963034188 @default.
- W4206156949 cites W2964437805 @default.
- W4206156949 cites W2970176447 @default.
- W4206156949 cites W2970319046 @default.
- W4206156949 cites W2973196346 @default.
- W4206156949 cites W2976567048 @default.
- W4206156949 cites W2990094993 @default.
- W4206156949 cites W3012877930 @default.
- W4206156949 cites W3015367136 @default.
- W4206156949 cites W3015408118 @default.
- W4206156949 cites W3016318765 @default.
- W4206156949 cites W3088429244 @default.
- W4206156949 cites W3095018827 @default.
- W4206156949 cites W3095475868 @default.
- W4206156949 cites W3118452175 @default.
- W4206156949 cites W3135210570 @default.
- W4206156949 cites W3157380812 @default.
- W4206156949 doi "https://doi.org/10.1016/j.apcatb.2021.121029" @default.
- W4206156949 hasPublicationYear "2022" @default.
- W4206156949 type Work @default.
- W4206156949 citedByCount "61" @default.
- W4206156949 countsByYear W42061569492022 @default.
- W4206156949 countsByYear W42061569492023 @default.
- W4206156949 crossrefType "journal-article" @default.
- W4206156949 hasAuthorship W4206156949A5005398821 @default.
- W4206156949 hasAuthorship W4206156949A5006164086 @default.
- W4206156949 hasAuthorship W4206156949A5013134790 @default.
- W4206156949 hasAuthorship W4206156949A5025324849 @default.
- W4206156949 hasAuthorship W4206156949A5035801000 @default.
- W4206156949 hasAuthorship W4206156949A5039762889 @default.
- W4206156949 hasAuthorship W4206156949A5041521616 @default.
- W4206156949 hasAuthorship W4206156949A5042022186 @default.
- W4206156949 hasAuthorship W4206156949A5046111523 @default.
- W4206156949 hasAuthorship W4206156949A5051812556 @default.
- W4206156949 hasAuthorship W4206156949A5059698647 @default.
- W4206156949 hasAuthorship W4206156949A5067268817 @default.
- W4206156949 hasAuthorship W4206156949A5073300113 @default.
- W4206156949 hasConcept C104779481 @default.
- W4206156949 hasConcept C127413603 @default.