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- W4206195220 abstract "Considering the stable compound Me3GeSiCi3 (1) as a potential nucleophile-induced source of SiCl2 moieties and to evaluate the properties of Me2Ge(SiCl3)2 as nucleophile-induced source of SiCh and GeMe2 moieties that could be generated by a kind of a domino-α-elimination, alkylidenediphosphane 5 (Me3Si)2CP-PRR' (R = tBu, R' = iPr) was chosen as a new multifunctional trapping reagent for six-electron species SiCl2 and GeMe2. Reaction of 1 with 5 leads to the formation of a stable 2-phospha-1,3-disiletane-ring system. This observation indicates that trichlorosilylgermanes will be of importance as sources of generation of nucleophile-stabilized dichlorosilylene under very mild conditions." @default.
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- W4206195220 date "2003-09-26" @default.
- W4206195220 modified "2023-10-14" @default.
- W4206195220 title "Some New Nucleophile‐Induced Reactions Involving SiCl <sub>2</sub> , GeCl <sub>2</sub> and GeMe <sub>2</sub> Transfer" @default.
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- W4206195220 doi "https://doi.org/10.1002/9783527619924.ch35" @default.
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