FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4206254416> ?p ?o ?g. }

• W4206254416 endingPage "38888" @default.
• W4206254416 startingPage "38880" @default.
• W4206254416 abstract "Sulfide solid electrolytes with high ionic conductivity and high air stability must be developed for manufacturing sulfide all-solid-state batteries. Li10GeP2S12-type and argyrodite-type solid electrolytes exhibit a high ionic conductivity of ∼10-2 S cm-1 at room temperature, while emitting toxic H2S gas when exposed to air. We focused on hexagonal Li4SnS4 prepared by mechanochemical treatment because it comprises air-stable SnS4 tetrahedra and shows higher ionic conductivity than orthorhombic Li4SnS4 prepared by solid-phase synthesis. Herein, to enhance the ionic conductivity of hexagonal Li4SnS4, LiI was added to Li4SnS4 by mechanochemical treatment. The ionic conductivity of 0.43LiI·0.57Li4SnS4 increased by 3.6 times compared with that of Li4SnS4. XRD patterns of Li4SnS4 with LiI showed peak-shifting to lower angles, indicating that introduction of I-, which has a large ionic radius, expanded the Li conduction paths. Furthermore, Li3PS4, which is the most air-stable in the Li2S-P2S5 system and has higher ionic conductivity than Li4SnS4, was added to the LiI-Li4SnS4 system. We found that 0.37LiI·0.25Li3PS4·0.38Li4SnS4 sintered at 200 °C showed the highest ionic conductivity of 5.5 × 10-4 S cm-1 at 30 °C in the hexagonal Li4SnS4-based solid electrolytes. The rate performance of an all-solid-state battery using 0.37LiI·0.25Li3PS4·0.38Li4SnS4 heated at 200 °C was higher than those obtained using Li4SnS4 and 0.43LiI·0.57Li4SnS4. In addition, it exhibited similar air stability to Li4SnS4 by formation of LiI·3H2O in air. Therefore, addition of LiI and Li3PS4 to hexagonal Li4SnS4 by mechanochemical treatment is an effective way to enhance ionic conductivity without decreasing the air stability of Li4SnS4." @default.
• W4206254416 created "2022-01-26" @default.
• W4206254416 creator A5001864383 @default.
• W4206254416 creator A5076397746 @default.
• W4206254416 creator A5087500856 @default.
• W4206254416 date "2021-01-01" @default.
• W4206254416 modified "2023-10-02" @default.
• W4206254416 title "Mechanochemical synthesis of air-stable hexagonal Li₄SnS₄-based solid electrolytes containing LiI and Li₃PS₄" @default.
• W4206254416 cites W1989188830 @default.
• W4206254416 cites W1997393957 @default.
• W4206254416 cites W2030515179 @default.
• W4206254416 cites W2032033599 @default.
• W4206254416 cites W2033229634 @default.
• W4206254416 cites W2035049672 @default.
• W4206254416 cites W2048590072 @default.
• W4206254416 cites W2056146245 @default.
• W4206254416 cites W2058761265 @default.
• W4206254416 cites W2070175377 @default.
• W4206254416 cites W2079607738 @default.
• W4206254416 cites W2130639370 @default.
• W4206254416 cites W2153511586 @default.
• W4206254416 cites W2205938059 @default.
• W4206254416 cites W2264927291 @default.
• W4206254416 cites W2321696461 @default.
• W4206254416 cites W2325139963 @default.
• W4206254416 cites W2475974565 @default.
• W4206254416 cites W2612819267 @default.
• W4206254416 cites W2790472672 @default.
• W4206254416 cites W2792592857 @default.
• W4206254416 cites W2803904599 @default.
• W4206254416 cites W2885366286 @default.
• W4206254416 cites W2886981055 @default.
• W4206254416 cites W2889473873 @default.
• W4206254416 cites W2891911880 @default.
• W4206254416 cites W2914183659 @default.
• W4206254416 cites W2941723922 @default.
• W4206254416 cites W2943535768 @default.
• W4206254416 cites W2965606732 @default.
• W4206254416 cites W2982336075 @default.
• W4206254416 cites W2986854664 @default.
• W4206254416 cites W2996374533 @default.
• W4206254416 cites W3033821097 @default.
• W4206254416 cites W3117860383 @default.
• W4206254416 cites W3137682745 @default.
• W4206254416 cites W3166079465 @default.
• W4206254416 cites W3175473043 @default.
• W4206254416 cites W4244932725 @default.
• W4206254416 doi "https://doi.org/10.1039/d1ra06466e" @default.
• W4206254416 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35493219" @default.
• W4206254416 hasPublicationYear "2021" @default.
• W4206254416 type Work @default.
• W4206254416 citedByCount "5" @default.
• W4206254416 countsByYear W42062544162022 @default.
• W4206254416 countsByYear W42062544162023 @default.
• W4206254416 crossrefType "journal-article" @default.
• W4206254416 hasAuthorship W4206254416A5001864383 @default.
• W4206254416 hasAuthorship W4206254416A5076397746 @default.
• W4206254416 hasAuthorship W4206254416A5087500856 @default.
• W4206254416 hasBestOaLocation W42062544161 @default.
• W4206254416 hasConcept C109883240 @default.
• W4206254416 hasConcept C113196181 @default.
• W4206254416 hasConcept C115624301 @default.
• W4206254416 hasConcept C131540310 @default.
• W4206254416 hasConcept C138679309 @default.
• W4206254416 hasConcept C138999460 @default.
• W4206254416 hasConcept C145148216 @default.
• W4206254416 hasConcept C147789679 @default.
• W4206254416 hasConcept C17525397 @default.
• W4206254416 hasConcept C178790620 @default.
• W4206254416 hasConcept C179104552 @default.
• W4206254416 hasConcept C185592680 @default.
• W4206254416 hasConcept C191897082 @default.
• W4206254416 hasConcept C192562407 @default.
• W4206254416 hasConcept C2182769 @default.
• W4206254416 hasConcept C2780596425 @default.
• W4206254416 hasConcept C37243968 @default.
• W4206254416 hasConcept C43617362 @default.
• W4206254416 hasConcept C54998646 @default.
• W4206254416 hasConcept C68801617 @default.
• W4206254416 hasConcept C8010536 @default.
• W4206254416 hasConceptScore W4206254416C109883240 @default.
• W4206254416 hasConceptScore W4206254416C113196181 @default.
• W4206254416 hasConceptScore W4206254416C115624301 @default.
• W4206254416 hasConceptScore W4206254416C131540310 @default.
• W4206254416 hasConceptScore W4206254416C138679309 @default.
• W4206254416 hasConceptScore W4206254416C138999460 @default.
• W4206254416 hasConceptScore W4206254416C145148216 @default.
• W4206254416 hasConceptScore W4206254416C147789679 @default.
• W4206254416 hasConceptScore W4206254416C17525397 @default.
• W4206254416 hasConceptScore W4206254416C178790620 @default.
• W4206254416 hasConceptScore W4206254416C179104552 @default.
• W4206254416 hasConceptScore W4206254416C185592680 @default.
• W4206254416 hasConceptScore W4206254416C191897082 @default.
• W4206254416 hasConceptScore W4206254416C192562407 @default.
• W4206254416 hasConceptScore W4206254416C2182769 @default.
• W4206254416 hasConceptScore W4206254416C2780596425 @default.
• W4206254416 hasConceptScore W4206254416C37243968 @default.
• W4206254416 hasConceptScore W4206254416C43617362 @default.

• next