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- W4206261469 abstract "There have been several studies on the solvolysis mechanisms for alkanesulfonyl chlorides (RSO2Cl) and arenesulfonyl chlorides (ArSO2Cl). The earlier of these studies were reviewed a little over thirty years ago by Gordon, Maskill and Ruasse (Chem. Soc. Rev.1989, 18, 123-151) in a contribution entitled Sulfonyl Transfer Reactions. The present review will emphasize more recent contributions and, in particular, the application of the extended Grunwald-Winstein equation and kinetic solvent isotope effects to the solvolysis reactions. There is also an appreciable number of reports concerning the corresponding anhydrides with the chloride leaving group replaced by the appropriate sulfonate leaving group, concerning sulfamoyl chlorides (ZZ'NSO2Cl) with Z and Z' being alkyl or aryl and concerning the solvolysis of chlorosulfate esters (alkoxy- or aryloxysulfonyl chlorides), with the structures ROSO2Cl or ArOSO2Cl. The solvolyses of these additional types of sulfur(VI) substrates will be the topics of a future review." @default.
- W4206261469 created "2022-01-26" @default.
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- W4206261469 date "2022-01-17" @default.
- W4206261469 modified "2023-09-25" @default.
- W4206261469 title "Mechanistic studies of the solvolysis of alkanesulfonyl and arenesulfonyl halides" @default.
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- W4206261469 doi "https://doi.org/10.3762/bjoc.18.13" @default.
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