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- W4206427115 abstract "1, 2-Dichlorodisilanes are prepared by reaction of silyl metal compounds with dichlorosilanes and subsequent chlorination. Alternatively, 1, 2-dichlorodisilanes are obtained by insertion of a silylene in the Si-CI bond of dichlorosilanes. Dehalogenation of 1, 2-dichlorodisilanes with magnesium leads to cyclic oligosilanes or vicinally dimetallated species. Ab initio calculations show that coordinated disilenes are plausible intermediates in some of these reactions." @default.
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- W4206427115 date "2005-07-26" @default.
- W4206427115 modified "2023-10-03" @default.
- W4206427115 title "Synthesis and Reactions of Chlorinated Oligosilanes" @default.
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- W4206427115 doi "https://doi.org/10.1002/9783527620777.ch55c" @default.
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