FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4206503701> ?p ?o ?g. }

• W4206503701 endingPage "1917" @default.
• W4206503701 startingPage "1899" @default.
• W4206503701 abstract "High yields of novel macropolyhedral selenaboranes are reported. Reactions of the monoanions of the syn- and anti-isomers of B18H22 with powdered selenium in THF variously give new macropolyhedral selenaboranes: 19-vertex [SeB18H19]- anion 1, 19-vertex [SeB18H21]- anion 2, 20-vertex [Se2B18H19]- anion 3, and 19-vertex [Se2B17H18]- anion 4. Single-cluster [hypho-Se2B6H9]- anion 5 and neutral arachno-Se2B7H96 also result. All of the macropolyhedrals 1, 2, 3, and 4 are characterized by NMR spectroscopy and mass spectrometry, and by single-crystal X-ray diffraction analyses. Anions 1 and 2 each consist of an 11-vertex subcluster joined by a common two-boron edge to a 10-vertex subcluster. Anion 3 consists of an 11-vertex subcluster joined by a common boron atom and an interboron link to an arachno-type 10-vertex subcluster. Unusually, anion 3 incorporates a hexagonal pyramidal intracluster structural motif in its 11-vertex subcluster. Anion 4 entails two arachno-type 10-vertex subclusters joined by a common boron atom, and with an additional intercluster boron-boron link. NMR data for syn-B18H22 and its mono- and dianions 7 and 8 and single-crystal X-ray diffraction results for these anions and also the monoanion 9 of anti-B18H22 are also reported. The oxaborane [μ-(8,9)-O-syn-B18H20]2- dianion 10 was serendipitously formed during the work and also characterized by a single-crystal X-ray diffraction study. Experimental NMR and structural findings are supported by DFT calculations throughout." @default.
• W4206503701 created "2022-01-25" @default.
• W4206503701 creator A5004952595 @default.
• W4206503701 creator A5005871307 @default.
• W4206503701 creator A5031601984 @default.
• W4206503701 creator A5041587523 @default.
• W4206503701 creator A5047135351 @default.
• W4206503701 creator A5071164987 @default.
• W4206503701 creator A5088639816 @default.
• W4206503701 creator A5091708807 @default.
• W4206503701 date "2022-01-20" @default.
• W4206503701 modified "2023-10-16" @default.
• W4206503701 title "Macropolyhedral Chalcogenaboranes: Insertion of Selenium into the Isomers of B₁₈H₂₂" @default.
• W4206503701 cites W1785834505 @default.
• W4206503701 cites W181749733 @default.
• W4206503701 cites W1894017489 @default.
• W4206503701 cites W1964994718 @default.
• W4206503701 cites W1969360633 @default.
• W4206503701 cites W1974084853 @default.
• W4206503701 cites W1974362797 @default.
• W4206503701 cites W1979000552 @default.
• W4206503701 cites W1984204903 @default.
• W4206503701 cites W1985644572 @default.
• W4206503701 cites W2000559020 @default.
• W4206503701 cites W2002225321 @default.
• W4206503701 cites W2004338350 @default.
• W4206503701 cites W2006378565 @default.
• W4206503701 cites W2007450839 @default.
• W4206503701 cites W2011066877 @default.
• W4206503701 cites W2011111749 @default.
• W4206503701 cites W2024550610 @default.
• W4206503701 cites W2025313938 @default.
• W4206503701 cites W2027157864 @default.
• W4206503701 cites W2037781961 @default.
• W4206503701 cites W2038470770 @default.
• W4206503701 cites W2044582311 @default.
• W4206503701 cites W2048083900 @default.
• W4206503701 cites W2051089405 @default.
• W4206503701 cites W2056382935 @default.
• W4206503701 cites W2059205366 @default.
• W4206503701 cites W2066134635 @default.
• W4206503701 cites W2070215083 @default.
• W4206503701 cites W2074444788 @default.
• W4206503701 cites W2088107939 @default.
• W4206503701 cites W2093102230 @default.
• W4206503701 cites W2120810251 @default.
• W4206503701 cites W2121237359 @default.
• W4206503701 cites W2123337591 @default.
• W4206503701 cites W2132454074 @default.
• W4206503701 cites W2155398060 @default.
• W4206503701 cites W2191055274 @default.
• W4206503701 cites W2259964822 @default.
• W4206503701 cites W2327721802 @default.
• W4206503701 cites W2401289374 @default.
• W4206503701 cites W2478552450 @default.
• W4206503701 cites W2885325920 @default.
• W4206503701 cites W2946405479 @default.
• W4206503701 cites W2949500592 @default.
• W4206503701 cites W2952320316 @default.
• W4206503701 cites W2958615394 @default.
• W4206503701 cites W2972418391 @default.
• W4206503701 cites W3005927025 @default.
• W4206503701 cites W3006144386 @default.
• W4206503701 cites W3041769782 @default.
• W4206503701 cites W3097565204 @default.
• W4206503701 cites W3122611986 @default.
• W4206503701 cites W3137202605 @default.
• W4206503701 cites W3216651724 @default.
• W4206503701 cites W561405111 @default.
• W4206503701 doi "https://doi.org/10.1021/acs.inorgchem.1c03018" @default.
• W4206503701 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35049289" @default.
• W4206503701 hasPublicationYear "2022" @default.
• W4206503701 type Work @default.
• W4206503701 citedByCount "2" @default.
• W4206503701 countsByYear W42065037012022 @default.
• W4206503701 countsByYear W42065037012023 @default.
• W4206503701 crossrefType "journal-article" @default.
• W4206503701 hasAuthorship W4206503701A5004952595 @default.
• W4206503701 hasAuthorship W4206503701A5005871307 @default.
• W4206503701 hasAuthorship W4206503701A5031601984 @default.
• W4206503701 hasAuthorship W4206503701A5041587523 @default.
• W4206503701 hasAuthorship W4206503701A5047135351 @default.
• W4206503701 hasAuthorship W4206503701A5071164987 @default.
• W4206503701 hasAuthorship W4206503701A5088639816 @default.
• W4206503701 hasAuthorship W4206503701A5091708807 @default.
• W4206503701 hasConcept C114614502 @default.
• W4206503701 hasConcept C115624301 @default.
• W4206503701 hasConcept C132525143 @default.
• W4206503701 hasConcept C145148216 @default.
• W4206503701 hasConcept C178790620 @default.
• W4206503701 hasConcept C185592680 @default.
• W4206503701 hasConcept C32909587 @default.
• W4206503701 hasConcept C33923547 @default.
• W4206503701 hasConcept C501308230 @default.
• W4206503701 hasConcept C71240020 @default.
• W4206503701 hasConcept C73922627 @default.
• W4206503701 hasConcept C8010536 @default.
• W4206503701 hasConcept C80899671 @default.

• next