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- W4206514018 abstract "Utilization of high energy ultraviolet (UV) and visible (Vis) light region of solar spectrum through photocatalytic processes for environmental remediation, energy conversion, and organic transformations have long been pursued. However, efficient harvesting and utilization of abundant and low energy near-infrared (NIR) light photons for such applications is a demanding quest in photocatalysis. The exceptional photophysical properties of upconversion nanoparticles (UCNP) such as large antistokes shifts, sharp emission spectra, and long excited-state lifetimes have made them a promising and advantageous alternative to conventional fluorescent materials. Solar light consists of about 52% of NIR region, therefore, the effective utilization of NIR light for photocatalysis is one of the current issues. In this regard, the lanthanide-doped upconversion materials have been recognized as promising candidates for the absorption of longer wavelength NIR photons and their subsequent conversion into high energy (UV and Vis) radiations. Thus, the integration of these lanthanide-doped upconversion materials with other semiconductors could be of great importance for the fabrication of broad spectrum active photocatalytic systems. In this regard, this book chapter aims at basic understanding of fundamentals of photocatalysis, upconversion phenomenon, major strategies employed for the utilization of NIR region of solar spectrum using upconversion based photocatalytic systems for environmental remediation, energy conversion, and organic transformations along with the involved mechanisms. Finally, the challenges and future perspectives in upconversion based photocatalysis field have been discussed." @default.
- W4206514018 created "2022-01-25" @default.
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- W4206514018 date "2022-01-01" @default.
- W4206514018 modified "2023-09-25" @default.
- W4206514018 title "Upconversion nanomaterials for photocatalytic applications" @default.
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- W4206514018 doi "https://doi.org/10.1016/b978-0-12-822842-5.00014-5" @default.
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