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- W4206646576 abstract "Abstract Herein we disclose an iron‐catalyzed cross‐coupling reaction of propargyl ethers with Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a facile preparation of optically active allenes via efficient chirality transfer. Various tri‐ and tetrasubstituted fluoroalkyl allenes can be obtained in good to excellent yields. In addition, an iron‐catalyzed cross‐coupling of Grignard reagents with α‐alkynyl oxetanes and tetrahydrofurans is disclosed herein, which constitutes a straightforward approach towards fully substituted β‐ or γ‐allenols, respectively." @default.
- W4206646576 created "2022-01-26" @default.
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- W4206646576 date "2021-09-03" @default.
- W4206646576 modified "2023-10-17" @default.
- W4206646576 title "Iron‐Catalyzed Cross‐Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols" @default.
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- W4206646576 doi "https://doi.org/10.1002/ange.202106742" @default.
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