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- W4206723897 endingPage "120" @default.
- W4206723897 startingPage "47" @default.
- W4206723897 abstract "Structures of lithium organics can basically be approached either by diffraction, spectroscopic or by computational methods. This chapter is concerned with structures derived from experimental methods, either from powder diffraction techniques or from single crystal structure determination. It outlines the basic building principles of the molecular architectures of lithium organics. The chapter explains the virtual metamorphosis of the cubic salt structure to the lithium organic tetramer. Addition of neutral Lewis-bases like diethyl ether, tetrahydrofuran, dimethoxy methane, tetramethylethylene diamine, pentamethyldiethylene triamine or various crown ethers, commonly referred to as donor-bases, to aggregated lithium organics normally decreases their degree of aggregation. Cyclopropane and cyclopropene exhibit a remarkable chemical applicability, predominantly due to their steric strain. The chapter presents lithiated R2C and RC species, hence lithium organics in which only two substituents or one group is bonded to the metalated center." @default.
- W4206723897 created "2022-01-25" @default.
- W4206723897 creator A5026369423 @default.
- W4206723897 creator A5050509238 @default.
- W4206723897 date "2004-04-23" @default.
- W4206723897 modified "2023-10-17" @default.
- W4206723897 title "Lead structures in lithium organic chemistry" @default.
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