Matches in SemOpenAlex for { <https://semopenalex.org/work/W4206760931> ?p ?o ?g. }
- W4206760931 endingPage "111683" @default.
- W4206760931 startingPage "111683" @default.
- W4206760931 abstract "The surface properties of a catalyst support not only influence the chemical states of the impregnated metals, but also the catalytic performance. Here, we systematically investigated the role of support morphology and defect concentration on the catalytic activity for dry reforming of methane (DRM) by comparing three-dimensional (3D) and two-dimensional (2D) aluminosilicate, borosilicate, and deboronated MCM tWenty-tWo (MWW)-type catalysts. Changes in the surface properties by delamination and/or deboronation as well as their influence on the formation of nickel silicates were experimentally demonstrated. Density functional theory (DFT) calculations were also performed to estimate the stabilization of metallic Ni clusters by the introduction of silanol defect sites on the MWW-type support. The delaminated–deboronated 2D MWW-type catalyst with the highest concentration of nickel silicates, and accordingly, the highest amount of silanol defect sites exhibited remarkable CH4 and CO2 conversions as well as stability for DRM. Unlike conventional Ni/γ-Al2O3, the Ni species in nickel silicate 2D MWW-type catalysts were readily reduced to metallic Ni even without pre-reduction by H2, which is advantageous for practical applications." @default.
- W4206760931 created "2022-01-25" @default.
- W4206760931 creator A5001599336 @default.
- W4206760931 creator A5014146991 @default.
- W4206760931 creator A5029158136 @default.
- W4206760931 creator A5046578494 @default.
- W4206760931 creator A5064895380 @default.
- W4206760931 creator A5076132049 @default.
- W4206760931 date "2022-02-01" @default.
- W4206760931 modified "2023-09-26" @default.
- W4206760931 title "Defect-induced formation of nickel silicates on two-dimensional MWW-type catalysts promoting catalytic activity for dry reforming of methane" @default.
- W4206760931 cites W1500390421 @default.
- W4206760931 cites W1501468991 @default.
- W4206760931 cites W1898724159 @default.
- W4206760931 cites W1966750682 @default.
- W4206760931 cites W1968058991 @default.
- W4206760931 cites W1980122368 @default.
- W4206760931 cites W1981368803 @default.
- W4206760931 cites W1990999710 @default.
- W4206760931 cites W1997087124 @default.
- W4206760931 cites W2000874485 @default.
- W4206760931 cites W2007751296 @default.
- W4206760931 cites W2019926744 @default.
- W4206760931 cites W2030971064 @default.
- W4206760931 cites W2035433800 @default.
- W4206760931 cites W2050257746 @default.
- W4206760931 cites W2052606568 @default.
- W4206760931 cites W2054987672 @default.
- W4206760931 cites W2055141821 @default.
- W4206760931 cites W2055149034 @default.
- W4206760931 cites W2070103756 @default.
- W4206760931 cites W2075044515 @default.
- W4206760931 cites W2208938795 @default.
- W4206760931 cites W2230244691 @default.
- W4206760931 cites W2288362353 @default.
- W4206760931 cites W2319439249 @default.
- W4206760931 cites W2480367813 @default.
- W4206760931 cites W2734737605 @default.
- W4206760931 cites W2767485564 @default.
- W4206760931 cites W2799338230 @default.
- W4206760931 cites W2804918031 @default.
- W4206760931 cites W2810773326 @default.
- W4206760931 cites W2842788124 @default.
- W4206760931 cites W2885818703 @default.
- W4206760931 cites W2888838181 @default.
- W4206760931 cites W2912300834 @default.
- W4206760931 cites W2947594891 @default.
- W4206760931 cites W2986877135 @default.
- W4206760931 cites W2995711723 @default.
- W4206760931 cites W2999115890 @default.
- W4206760931 cites W2999613430 @default.
- W4206760931 cites W3045670433 @default.
- W4206760931 cites W3083592804 @default.
- W4206760931 cites W3091210043 @default.
- W4206760931 cites W3096425375 @default.
- W4206760931 cites W3156469717 @default.
- W4206760931 cites W3171085119 @default.
- W4206760931 cites W3195619548 @default.
- W4206760931 cites W66869866 @default.
- W4206760931 cites W76900207 @default.
- W4206760931 doi "https://doi.org/10.1016/j.micromeso.2022.111683" @default.
- W4206760931 hasPublicationYear "2022" @default.
- W4206760931 type Work @default.
- W4206760931 citedByCount "0" @default.
- W4206760931 crossrefType "journal-article" @default.
- W4206760931 hasAuthorship W4206760931A5001599336 @default.
- W4206760931 hasAuthorship W4206760931A5014146991 @default.
- W4206760931 hasAuthorship W4206760931A5029158136 @default.
- W4206760931 hasAuthorship W4206760931A5046578494 @default.
- W4206760931 hasAuthorship W4206760931A5064895380 @default.
- W4206760931 hasAuthorship W4206760931A5076132049 @default.
- W4206760931 hasConcept C127413603 @default.
- W4206760931 hasConcept C161790260 @default.
- W4206760931 hasConcept C178790620 @default.
- W4206760931 hasConcept C179104552 @default.
- W4206760931 hasConcept C185592680 @default.
- W4206760931 hasConcept C191897082 @default.
- W4206760931 hasConcept C192562407 @default.
- W4206760931 hasConcept C194439259 @default.
- W4206760931 hasConcept C2777335606 @default.
- W4206760931 hasConcept C2777581007 @default.
- W4206760931 hasConcept C42360764 @default.
- W4206760931 hasConcept C504270822 @default.
- W4206760931 hasConcept C516920438 @default.
- W4206760931 hasConcept C544153396 @default.
- W4206760931 hasConcept C7304416 @default.
- W4206760931 hasConcept C85704489 @default.
- W4206760931 hasConceptScore W4206760931C127413603 @default.
- W4206760931 hasConceptScore W4206760931C161790260 @default.
- W4206760931 hasConceptScore W4206760931C178790620 @default.
- W4206760931 hasConceptScore W4206760931C179104552 @default.
- W4206760931 hasConceptScore W4206760931C185592680 @default.
- W4206760931 hasConceptScore W4206760931C191897082 @default.
- W4206760931 hasConceptScore W4206760931C192562407 @default.
- W4206760931 hasConceptScore W4206760931C194439259 @default.
- W4206760931 hasConceptScore W4206760931C2777335606 @default.
- W4206760931 hasConceptScore W4206760931C2777581007 @default.
- W4206760931 hasConceptScore W4206760931C42360764 @default.