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• W4206814599 abstract "Herein, we report a facile and highly atom-economic approach to 2-phosphafurans by using simple 2-chloroethylphosphine and acetylenic ketones. The key step of this protocol utilizes the Lewis acidity of electrophilic phosphinidenes to induce an intramolecular cyclization with enones. Dearomative hetero-Diels-Alder reactions of 2-phosphafurans provide two series of bicyclic phosphacycles. This rare synthetic application of Lewis acidity of electrophilic phosphinidene complexes represents a new frontier of phosphinidene chemistry." @default.
• W4206814599 created "2022-01-25" @default.
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• W4206814599 date "2022-01-10" @default.
• W4206814599 modified "2023-10-14" @default.
• W4206814599 title "Intramolecular Activation of Enones by Electrophilic Phosphinidene Complexes to Construct 2-Phosphafurans" @default.
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• W4206814599 doi "https://doi.org/10.1021/acs.orglett.1c04281" @default.
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