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- W4206959098 abstract "• UiO-66-NH 2 was in-situ grown in PES substrates under room temperature. • the preparation process did not involve polar aprotic solvent. • the obtained membrane shows excellent molecular separation performance. • the obtained membrane has good water stability. In-situ growth of UiO-66-NH 2 in ordinary porous polymeric substrates offers promising opportunities to eliminate interfacial defects in mixed matrix membranes (MMMs). However, this strategy is still hard to be realized because conventional hydrothermal synthesis of UiO-66-NH 2 involves harsh conditions (e.g., high temperatures, and polar aprotic solvents), which are destructive to ordinary polymer. Herein, UiO-66-NH 2 was in-situ grown in polymeric substrates under room temperature via a successive immersion of a porous polyether sulfones substrate in a Zr 4+ formic acid/ethanol solution and a 2-aminoterephthalic acid ethanol/formic acid/water solution. Attenuated total refraction Fourier transform infrared and X-ray diffraction characterizations demonstrated the successful incorporation of UiO-66-NH 2 in the substrate. The optimized membrane possessed a high pure water permeance of 209.5 L -2 h −1 bar −1 and rejections higher than 99.5% towards small molecules of Congo Red, xylene brilliant cyanin G, and Rose Bengal sodium salt. More importantly, after a 5-day immersion in water or an intense ultrasonication treatment, the membrane showed no significant change in separation performance, suggesting its excellent stability. The novel strategy regarding MMMs with UiO-66-NH 2 in-situ growth disclosed in this study paves the way to develop advanced UiO-66-NH 2 membranes toward sustainable molecular separation in environmental applications." @default.
- W4206959098 created "2022-01-26" @default.
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- W4206959098 date "2022-05-01" @default.
- W4206959098 modified "2023-09-29" @default.
- W4206959098 title "In-situ growth of UiO-66-NH2 in porous polymeric substrates at room temperature for fabrication of mixed matrix membranes with fast molecular separation performance" @default.
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- W4206959098 doi "https://doi.org/10.1016/j.cej.2022.134804" @default.
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