Matches in SemOpenAlex for { <https://semopenalex.org/work/W4207024881> ?p ?o ?g. }
- W4207024881 endingPage "530" @default.
- W4207024881 startingPage "519" @default.
- W4207024881 abstract "Carbon dioxide (CO2) fixation into valuable chemicals is of great significance, but a molecular level rational design of catalysts remains a challenge. Herein, based on the proposal of a “spring-loaded” mechanism, a family of phenolic hydroxyl imidazolium salt-based ionic liquids was designed for CO2 cycloaddition with epoxides into cyclic carbonates. The cation-anion interaction intensity was finely modulated through tailoring the position of the hydroxyl group. The moderate intensity endows superior nucleophilic leaving ability of the I− anion to provide strong C···I interaction for the rate-determining ring-opening step. The synergy of nucleophilic attack by the I− anion, electrophilic attack by a hydroxyl group, and corresponding stabilization effect enabled a high yield within a short reaction time, even at room temperature and atmospheric conditions. A volcano-type regulation of the spring-loaded mechanism was unraveled, revealing the crucial parameter in the designation of high-performing catalyst for CO2 transformation via cycloaddition." @default.
- W4207024881 created "2022-01-26" @default.
- W4207024881 creator A5010738468 @default.
- W4207024881 creator A5012278873 @default.
- W4207024881 creator A5014943042 @default.
- W4207024881 creator A5019357176 @default.
- W4207024881 creator A5022141835 @default.
- W4207024881 creator A5042241049 @default.
- W4207024881 creator A5074477190 @default.
- W4207024881 creator A5085891998 @default.
- W4207024881 date "2022-03-01" @default.
- W4207024881 modified "2023-10-16" @default.
- W4207024881 title "“Spring-loaded” mechanism for chemical fixation of carbon dioxide with epoxides" @default.
- W4207024881 cites W1966552331 @default.
- W4207024881 cites W1969141512 @default.
- W4207024881 cites W1979769822 @default.
- W4207024881 cites W2020959202 @default.
- W4207024881 cites W2049848523 @default.
- W4207024881 cites W2050081896 @default.
- W4207024881 cites W2055663482 @default.
- W4207024881 cites W2070939053 @default.
- W4207024881 cites W2088432736 @default.
- W4207024881 cites W2090962188 @default.
- W4207024881 cites W2115768460 @default.
- W4207024881 cites W2141980865 @default.
- W4207024881 cites W2156637912 @default.
- W4207024881 cites W2179674111 @default.
- W4207024881 cites W2301085974 @default.
- W4207024881 cites W2314530730 @default.
- W4207024881 cites W2322788072 @default.
- W4207024881 cites W2328022101 @default.
- W4207024881 cites W2329209079 @default.
- W4207024881 cites W2474294794 @default.
- W4207024881 cites W2510497129 @default.
- W4207024881 cites W2533257396 @default.
- W4207024881 cites W2547478084 @default.
- W4207024881 cites W2551556053 @default.
- W4207024881 cites W2552213207 @default.
- W4207024881 cites W2563844333 @default.
- W4207024881 cites W2607676583 @default.
- W4207024881 cites W2625935407 @default.
- W4207024881 cites W2746168731 @default.
- W4207024881 cites W2750450258 @default.
- W4207024881 cites W2770577765 @default.
- W4207024881 cites W2771222095 @default.
- W4207024881 cites W2786368684 @default.
- W4207024881 cites W2805106449 @default.
- W4207024881 cites W2889632453 @default.
- W4207024881 cites W2894848096 @default.
- W4207024881 cites W2903340698 @default.
- W4207024881 cites W2904698698 @default.
- W4207024881 cites W2918265156 @default.
- W4207024881 cites W2946498597 @default.
- W4207024881 cites W2947165468 @default.
- W4207024881 cites W2953530908 @default.
- W4207024881 cites W2976088245 @default.
- W4207024881 cites W2988232688 @default.
- W4207024881 cites W3004482724 @default.
- W4207024881 cites W3005711490 @default.
- W4207024881 cites W3009645750 @default.
- W4207024881 cites W3013712680 @default.
- W4207024881 cites W3019642045 @default.
- W4207024881 cites W3047466853 @default.
- W4207024881 cites W3082030425 @default.
- W4207024881 cites W3092197311 @default.
- W4207024881 cites W3111946337 @default.
- W4207024881 cites W3119760375 @default.
- W4207024881 cites W3120909899 @default.
- W4207024881 cites W3155440101 @default.
- W4207024881 cites W3196218432 @default.
- W4207024881 cites W4240569453 @default.
- W4207024881 cites W4243395139 @default.
- W4207024881 doi "https://doi.org/10.1016/j.checat.2021.12.023" @default.
- W4207024881 hasPublicationYear "2022" @default.
- W4207024881 type Work @default.
- W4207024881 citedByCount "20" @default.
- W4207024881 countsByYear W42070248812022 @default.
- W4207024881 countsByYear W42070248812023 @default.
- W4207024881 crossrefType "journal-article" @default.
- W4207024881 hasAuthorship W4207024881A5010738468 @default.
- W4207024881 hasAuthorship W4207024881A5012278873 @default.
- W4207024881 hasAuthorship W4207024881A5014943042 @default.
- W4207024881 hasAuthorship W4207024881A5019357176 @default.
- W4207024881 hasAuthorship W4207024881A5022141835 @default.
- W4207024881 hasAuthorship W4207024881A5042241049 @default.
- W4207024881 hasAuthorship W4207024881A5074477190 @default.
- W4207024881 hasAuthorship W4207024881A5085891998 @default.
- W4207024881 hasBestOaLocation W42070248811 @default.
- W4207024881 hasConcept C134121241 @default.
- W4207024881 hasConcept C145148216 @default.
- W4207024881 hasConcept C154881586 @default.
- W4207024881 hasConcept C159985019 @default.
- W4207024881 hasConcept C161790260 @default.
- W4207024881 hasConcept C178790620 @default.
- W4207024881 hasConcept C178907741 @default.
- W4207024881 hasConcept C185592680 @default.
- W4207024881 hasConcept C192562407 @default.
- W4207024881 hasConcept C199873434 @default.