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- W4207033720 abstract "This work has developed a new strategy of biogeochemical Fe(II) generators for activating microbial Fe(II) generation to immobilize Cd in soils through protons scavenging and coprecipitation. A new biochar modified magnetite (FeBC15) has been fabricated through a top-down method, with which microbial respiration can be stimulated in paddy soil. The FeBC15 exhibits a higher adsorption capacity for Cd than pristine magnetite (1.7 times). The results show that the available Cd can be reduced by 14.4% after adding FeBC15 compared to the control. More importantly, FeBC15 particles promote the conversion of MgCl2 - Cd to stable crystalline Fe/Al bound Cd under the incubation period. The enhanced pH and Fe(II) leads to a comparably lower Cd availability in soils than in pristine soils, which are supported by the enhanced relative abundance of Geobacter and Clostridium with the FeBC15 treatment (i.e. up to 7.44-7.68 × 109 copies/g soil). The Diffusive Gradients in Thin-films (DGT) study indicates that FeBC15 can lower the replenish capacity of soils (i.e. KdL values of 0.2-3.6 mL/g) to soil pore waters and limit root absorption. Pot experiments demonstrate that this strategy can alleviate the rice Cd content by 38.4% (< 0.2 mg/kg). This work paves a new pathway for reducing Cd uptake in rice, enabling sustainable remediation of paddy soil." @default.
- W4207033720 created "2022-01-26" @default.
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- W4207033720 date "2022-05-01" @default.
- W4207033720 modified "2023-09-28" @default.
- W4207033720 title "Biogeochemical Fe(II) generators as a new strategy for limiting Cd uptake by rice and its implication for agricultural sustainability" @default.
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- W4207033720 doi "https://doi.org/10.1016/j.scitotenv.2022.153306" @default.
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