Matches in SemOpenAlex for { <https://semopenalex.org/work/W4207035090> ?p ?o ?g. }
- W4207035090 endingPage "10989" @default.
- W4207035090 startingPage "10983" @default.
- W4207035090 abstract "Abstract Interfacially confined microenvironments have recently gained attention in catalysis, as they can be used to modulate reaction chemistry. The emergence of a 2D nanospace at the interface between a 2D material and its support can promote varying kinetic and energetic schemes based on molecular level confinement effects imposed in this reduced volume. We report on the use of a 2D oxide cover, bilayer silica, on catalytically active Pd(111) undergoing the CO oxidation reaction. We “uncover” mechanistic insights about the structure–activity relationship with and without a 2D silica overlayer using in situ IR and X‐ray spectroscopy and mass spectrometry methods. We find that the CO oxidation reaction on Pd(111) benefits from confinement effects imposed on surface adsorbates under 2D silica. This interaction results in a lower and more dispersed coverage of CO adsorbates with restricted CO adsorption geometries, which promote oxygen adsorption and lay the foundation for the formation of a reactive surface oxide that produces higher CO 2 formation rates than Pd alone." @default.
- W4207035090 created "2022-01-26" @default.
- W4207035090 creator A5007650561 @default.
- W4207035090 creator A5012193815 @default.
- W4207035090 creator A5034171462 @default.
- W4207035090 creator A5053922026 @default.
- W4207035090 creator A5061621593 @default.
- W4207035090 creator A5070392626 @default.
- W4207035090 creator A5080366404 @default.
- W4207035090 date "2021-03-30" @default.
- W4207035090 modified "2023-10-15" @default.
- W4207035090 title "Enhanced Catalysis under 2D Silica: A CO Oxidation Study" @default.
- W4207035090 cites W1973914062 @default.
- W4207035090 cites W1975280241 @default.
- W4207035090 cites W1978821720 @default.
- W4207035090 cites W1983269945 @default.
- W4207035090 cites W2002397717 @default.
- W4207035090 cites W2003099229 @default.
- W4207035090 cites W2010688010 @default.
- W4207035090 cites W2015358861 @default.
- W4207035090 cites W2023472611 @default.
- W4207035090 cites W2023554337 @default.
- W4207035090 cites W2030170042 @default.
- W4207035090 cites W2044409640 @default.
- W4207035090 cites W2052994912 @default.
- W4207035090 cites W2053459474 @default.
- W4207035090 cites W2067485371 @default.
- W4207035090 cites W2069019782 @default.
- W4207035090 cites W2077497579 @default.
- W4207035090 cites W2077784902 @default.
- W4207035090 cites W2094207399 @default.
- W4207035090 cites W2128468022 @default.
- W4207035090 cites W2130283800 @default.
- W4207035090 cites W2139636402 @default.
- W4207035090 cites W2143531360 @default.
- W4207035090 cites W2149590362 @default.
- W4207035090 cites W2150523237 @default.
- W4207035090 cites W2162810469 @default.
- W4207035090 cites W2259947560 @default.
- W4207035090 cites W2292770293 @default.
- W4207035090 cites W2302408606 @default.
- W4207035090 cites W2311902861 @default.
- W4207035090 cites W2327296903 @default.
- W4207035090 cites W2330580173 @default.
- W4207035090 cites W2333010159 @default.
- W4207035090 cites W2416191663 @default.
- W4207035090 cites W2464488763 @default.
- W4207035090 cites W2507813663 @default.
- W4207035090 cites W2507854244 @default.
- W4207035090 cites W2519678442 @default.
- W4207035090 cites W2591463622 @default.
- W4207035090 cites W2620503350 @default.
- W4207035090 cites W2623696367 @default.
- W4207035090 cites W2781908747 @default.
- W4207035090 cites W2785365961 @default.
- W4207035090 cites W2791252906 @default.
- W4207035090 cites W2801416781 @default.
- W4207035090 cites W2802118659 @default.
- W4207035090 cites W2807445555 @default.
- W4207035090 cites W2901086625 @default.
- W4207035090 cites W2920885759 @default.
- W4207035090 cites W2965536134 @default.
- W4207035090 cites W2966615668 @default.
- W4207035090 cites W2973093293 @default.
- W4207035090 cites W3007349634 @default.
- W4207035090 cites W3017636210 @default.
- W4207035090 cites W3046941411 @default.
- W4207035090 cites W4206419802 @default.
- W4207035090 doi "https://doi.org/10.1002/ange.202013801" @default.
- W4207035090 hasPublicationYear "2021" @default.
- W4207035090 type Work @default.
- W4207035090 citedByCount "1" @default.
- W4207035090 countsByYear W42070350902022 @default.
- W4207035090 crossrefType "journal-article" @default.
- W4207035090 hasAuthorship W4207035090A5007650561 @default.
- W4207035090 hasAuthorship W4207035090A5012193815 @default.
- W4207035090 hasAuthorship W4207035090A5034171462 @default.
- W4207035090 hasAuthorship W4207035090A5053922026 @default.
- W4207035090 hasAuthorship W4207035090A5061621593 @default.
- W4207035090 hasAuthorship W4207035090A5070392626 @default.
- W4207035090 hasAuthorship W4207035090A5080366404 @default.
- W4207035090 hasBestOaLocation W42070350903 @default.
- W4207035090 hasConcept C127413603 @default.
- W4207035090 hasConcept C147789679 @default.
- W4207035090 hasConcept C150394285 @default.
- W4207035090 hasConcept C161790260 @default.
- W4207035090 hasConcept C175583648 @default.
- W4207035090 hasConcept C178790620 @default.
- W4207035090 hasConcept C185592680 @default.
- W4207035090 hasConcept C192157962 @default.
- W4207035090 hasConcept C2775913835 @default.
- W4207035090 hasConcept C2779851234 @default.
- W4207035090 hasConcept C41625074 @default.
- W4207035090 hasConcept C42360764 @default.
- W4207035090 hasConcept C540031477 @default.
- W4207035090 hasConcept C55493867 @default.
- W4207035090 hasConcept C75473681 @default.
- W4207035090 hasConceptScore W4207035090C127413603 @default.