Matches in SemOpenAlex for { <https://semopenalex.org/work/W4207037267> ?p ?o ?g. }
- W4207037267 abstract "Abstract Generally, nanostructured polymer particles are prepared by 3D confined self‐assembly (3D‐CSA) of block copolymers (BCPs), while micelles are obtained through self‐assembly of BCPs in dilute solutions. Herein, a facile yet robust strategy is developed to regulate the assembled structures of BCP, poly(styrene‐ block ‐4‐vinylpyridine) (PS‐ b ‐P4VP), from nanostructured particles to micelles. The assemblies are prepared by an emulsion‐solvent diffusion‐induced self‐assembly route, which is conducted by dialysis. A key feature of this strategy is that a P4VP‐selective solvent (e.g., ethanol) is added to the dialysate to tune the interfacial behavior of the droplets and assembled structures of PS‐ b ‐P4VP. The authors’ results reveal that in the presence of slight ethanol, the surface and internal structural transitions of nanostructured particles are caused by changes in the interfacial selectivity and packing parameter. Interestingly, interfacial instability, which results in the formation of micelles, is observed when the dialysate contains 50 vol% ethanol or more. The reason can be ascribed to the decreased interface tension, which is induced by the increase in ethanol and enhanced solubility of P4VP. This facile strategy provides a new opportunity to bridge the gap between traditional 3D‐CSA and solution self‐assembly of BCPs, offering a promising route to engineer morphologies and nanostructures of polymeric assemblies." @default.
- W4207037267 created "2022-01-26" @default.
- W4207037267 creator A5009294094 @default.
- W4207037267 creator A5010065766 @default.
- W4207037267 creator A5022727895 @default.
- W4207037267 creator A5023303944 @default.
- W4207037267 creator A5066933145 @default.
- W4207037267 creator A5077072862 @default.
- W4207037267 creator A5089668613 @default.
- W4207037267 date "2022-01-29" @default.
- W4207037267 modified "2023-10-18" @default.
- W4207037267 title "Structure Regulation of Block Copolymer Assemblies in Emulsion Droplets by Adding a Selective Solvent" @default.
- W4207037267 cites W1493019192 @default.
- W4207037267 cites W2011263586 @default.
- W4207037267 cites W2048518514 @default.
- W4207037267 cites W2075370047 @default.
- W4207037267 cites W2092264487 @default.
- W4207037267 cites W2102516390 @default.
- W4207037267 cites W2169868793 @default.
- W4207037267 cites W2289309102 @default.
- W4207037267 cites W2314376682 @default.
- W4207037267 cites W2316241063 @default.
- W4207037267 cites W2327341071 @default.
- W4207037267 cites W2345572580 @default.
- W4207037267 cites W2750027892 @default.
- W4207037267 cites W2751155735 @default.
- W4207037267 cites W2885064598 @default.
- W4207037267 cites W2899288722 @default.
- W4207037267 cites W2912321905 @default.
- W4207037267 cites W2913513187 @default.
- W4207037267 cites W2921446552 @default.
- W4207037267 cites W2969652439 @default.
- W4207037267 cites W2999575851 @default.
- W4207037267 cites W3006060852 @default.
- W4207037267 cites W3032611264 @default.
- W4207037267 cites W3048553751 @default.
- W4207037267 cites W3093019175 @default.
- W4207037267 cites W3098496868 @default.
- W4207037267 cites W3117722754 @default.
- W4207037267 cites W3138215036 @default.
- W4207037267 cites W3186854028 @default.
- W4207037267 cites W3192390013 @default.
- W4207037267 cites W3196043711 @default.
- W4207037267 cites W4246757488 @default.
- W4207037267 doi "https://doi.org/10.1002/marc.202100845" @default.
- W4207037267 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35032147" @default.
- W4207037267 hasPublicationYear "2022" @default.
- W4207037267 type Work @default.
- W4207037267 citedByCount "3" @default.
- W4207037267 countsByYear W42070372672022 @default.
- W4207037267 countsByYear W42070372672023 @default.
- W4207037267 crossrefType "journal-article" @default.
- W4207037267 hasAuthorship W4207037267A5009294094 @default.
- W4207037267 hasAuthorship W4207037267A5010065766 @default.
- W4207037267 hasAuthorship W4207037267A5022727895 @default.
- W4207037267 hasAuthorship W4207037267A5023303944 @default.
- W4207037267 hasAuthorship W4207037267A5066933145 @default.
- W4207037267 hasAuthorship W4207037267A5077072862 @default.
- W4207037267 hasAuthorship W4207037267A5089668613 @default.
- W4207037267 hasConcept C100293340 @default.
- W4207037267 hasConcept C11268172 @default.
- W4207037267 hasConcept C118792377 @default.
- W4207037267 hasConcept C121332964 @default.
- W4207037267 hasConcept C127413603 @default.
- W4207037267 hasConcept C15920480 @default.
- W4207037267 hasConcept C159985019 @default.
- W4207037267 hasConcept C161790260 @default.
- W4207037267 hasConcept C171250308 @default.
- W4207037267 hasConcept C178790620 @default.
- W4207037267 hasConcept C184651966 @default.
- W4207037267 hasConcept C185592680 @default.
- W4207037267 hasConcept C186187911 @default.
- W4207037267 hasConcept C188027245 @default.
- W4207037267 hasConcept C192562407 @default.
- W4207037267 hasConcept C26856880 @default.
- W4207037267 hasConcept C2777566558 @default.
- W4207037267 hasConcept C2778123984 @default.
- W4207037267 hasConcept C2780471494 @default.
- W4207037267 hasConcept C42360764 @default.
- W4207037267 hasConcept C521977710 @default.
- W4207037267 hasConcept C62520636 @default.
- W4207037267 hasConcept C8892853 @default.
- W4207037267 hasConceptScore W4207037267C100293340 @default.
- W4207037267 hasConceptScore W4207037267C11268172 @default.
- W4207037267 hasConceptScore W4207037267C118792377 @default.
- W4207037267 hasConceptScore W4207037267C121332964 @default.
- W4207037267 hasConceptScore W4207037267C127413603 @default.
- W4207037267 hasConceptScore W4207037267C15920480 @default.
- W4207037267 hasConceptScore W4207037267C159985019 @default.
- W4207037267 hasConceptScore W4207037267C161790260 @default.
- W4207037267 hasConceptScore W4207037267C171250308 @default.
- W4207037267 hasConceptScore W4207037267C178790620 @default.
- W4207037267 hasConceptScore W4207037267C184651966 @default.
- W4207037267 hasConceptScore W4207037267C185592680 @default.
- W4207037267 hasConceptScore W4207037267C186187911 @default.
- W4207037267 hasConceptScore W4207037267C188027245 @default.
- W4207037267 hasConceptScore W4207037267C192562407 @default.
- W4207037267 hasConceptScore W4207037267C26856880 @default.
- W4207037267 hasConceptScore W4207037267C2777566558 @default.
- W4207037267 hasConceptScore W4207037267C2778123984 @default.